Radical Polymerization : New Developments.

Intro -- RADICAL POLYMERIZATIONNEW DEVELOPMENTS -- POLYMER SCIENCE AND TECHNOLOGY -- RADICAL POLYMERIZATIONNEW DEVELOPMENTS -- LIBRARY OF CONGRESS CATALOGING-IN-PUBLICATION DATA -- CONTENTS -- PREFACE -- CHAPTER 1. INTERFACE RADICAL REACTIONS OF FUNCTIONAL POLYPEROXIDES FOR FABRICATION OF THREE-DIMENSIONAL POLYMERIC STRUCTURES -- ABSTRACT -- INTRODUCTION -- EXPERIMENTAL -- Materials -- Grafting of FPPs to a Polyolefin Surface -- Formation of Hydrogels Grafted to Polypropylene Substrate by Radical Polymerization -- Formation of Grafted Hydrogels by Condensation Mechanism -- Stage 1. Grafting of PAAm to the Surface of PP Substrates -- Stage 2. Cross-Linking -- Formation of Porous Hydrogels -- Stage 1. Peroxidation of Silica Particles -- Stage 2. Grafting of PAAm -- Stage 3. Crosslinking of Hydrogels -- Stage 4. Leaching out Silica Particles from Hydrogel -- RESULTS AND DISCUSSION -- Prediction of Interfacial Interaction betweenFPP Film and Polymeric Substrate Surface -- Thermal Decomposition of FPPs -- Effect of FPP Structure on Surface Coverage -- FPP Grafting on PP Surface -- Mathematical Model of FPP Grafting -- Modification of the Peroxidized Polymer Surface withFunctional Monomers and Polysaccharides -- Covalent Grafting of Paam-Based Hydrogels to a PP Substrate by Radical Polymerization -- Covalent Grafting of Paam-Based Hydrogels TopSubstrate by Intermolecular Condensation -- Covalent Grafting of Paam to Dispersed Silica Surface andFormation of Porous Hydrogels with a Regular Pore Distribution -- CONCLUSION -- REFERENCES -- CHAPTER 2. BIOMACROMOLECULES IN RADICAL PROCESSES: INNOVATIVE STRATEGIES FOR THESYNTHESIS OF BIOMATERIALS -- ABSTRACT -- 1. INTRODUCTION -- 2. SYNTHESIS OF BIOMATERIALS BY RADICALPOLYMERIZATION OF BIOMACROMOLECULES DERIVATIVES -- 2.1. Chitosan -- 2.2. Dextran -- 2.3. Hyaluronic Acid -- 2.4. Cellulose -- 2.5. Starch.

2.6. Galactomannan, Guar Gum, Inulin and Pectin -- 2.7. Albumin -- 2.8. Gelatin -- 3. GRAFTING OF BIOMACROMOLECULES -- 3.1. Chitosan -- 3.2. Dextran -- 3.3. Starch -- 3.4. Guar Gum -- 3.5. Pectin -- 3.6. Inulin -- 3.7. Alginate -- 3.8. Collagen and Gelatin -- REFERENCES -- CHAPTER 3. NITROXIDE-MEDIATED PHOTO CONTROLLED/LIVING RADICAL POLYMERIZATION -- 1. INTRODUCTION -- 2. MOLECULAR WEIGHT CONTROL OF POLYMERS [37, 38] -- 3. EFFECT OF INITIATORS [43] -- 4. MECHANISMS [40] -- 5. PHOTO-ACID GENERATORS -- 5.1. Triarylsulfonium Salts [42, 44] -- 5.2. An Iron-Arene Complex [47] -- 6. STABILITY OF THE GROWING POLYMER CHAIN END [45] -- 7. SOLUTION POLYMERIZATION [46] -- 8. MOLECULAR DESIGN -- 8.1. Block Copolymerization Using a TEMPO Macromediator [39] -- 8.2. Graft Copolymerization Using TEMPO Supported on Polymer SideChains [48] -- CONCLUSIONS -- REFERENCES -- CHAPTER 4. ALKALINE ANION-EXCHANGE MEMBRANES PREPARED BY PLASMA POLYMERIZATION: SYNTHESIS, STRUCTURAL CHARACTERIZATION AND APPLICATION IN DIRECT ALCOHOL FUEL CELLS -- ABSTRACT -- 1. FUNDAMENTAL ASPECTS OF PLASMA POLYMERIZATION -- 2. GENERAL CHARACTERISTICS OF PLASMA POLYMER FILMS -- 3. ALKALINE ANION-EXCHANGE MEMBRANES PREPARED BY PLASMA POLYMERIZATION FOR APPLICATION IN DIRECT ALCOHOL FUEL CELLS (DAFCS) -- 3.1. Introduction -- 3.2. Synthesis of Plasma-Polymerized Alkaline Anion-Exchange Membrane -- 3.3. Characteristic Measurements of Membranes -- 3.4. Morphology of PVBC Membranes [39] -- 3.5. IEC Analysis [39] -- 3.6. Chemical Structure Characterization of the Membranes [35, 39] -- 3.7. Ionic Conductivity [35] -- 3.8. Thermal Stability [35] -- 4. SUMMARY -- REFERENCES -- CHAPTER 5. A REVIEW ON RADICAL POLYMERIZATION USED FOR DESIGN AND DEVELOPMENT OF BIOMATERIALS -- ABSTRACT -- ABBREVIATIONS -- Monomers -- Polymers -- Ligands -- 1. INTRODUCTION -- 2. FREE RADICAL POLYMERIZATION.

3. CONTROLLED/LIVING RADICAL POLYMERIZATION -- 3.1. Basic Concepts of Controlled/Living Radical Polymerization -- 3.2. Types of Controlled/Living Radical Polymerization -- 3.2.1. Atom Transfer Radical Polymerization: Kinetics and Mechanism -- 3.2.1.1.Carbohydrate Based Graft Copolymers -- 3.2.1.2.Carbohydrate Based Surface Graft Copolymers by ATRP -- 3.2.1.3. Carbohydrate Based Self-Assembled Copolymers by ATRP -- 3.2.2. Reversible Addition-Fragmentation Chain Transfer Polymerization -- 3.2.3. Nitroxide Mediated Polymerization (NMP) -- CONCLUSION -- ACKNOWLEDGEMENT -- REFERENCES -- CHAPTER 6. ADVANCEMENTS IN CONTROLLED RADICAL POLYMERIZATION FOR FUNCTIONAL POLYMERS -- ABSTRACT -- 1. INTRODUCTION -- 2. HISTORICAL EVOLUTION OF CRP -- 3. TYPES OF CONTROL RADICAL POLYMERIZATION -- 3.1. Nitroxide Mediated Polymerization (NMP) -- 3.2. Reversible Addition-Fragmentation Chain Transfer Polymerization -- 3.3 . Atom Transfer Radical Polymerization -- Basic Component of ATRP -- Catalyst -- Monomer -- Initiators -- Ligand -- 4. FUNCTIONALIZED POLYOLEFINS -- 4.1. Macro Monomer/ Macro Initiator ApproachFollowed by CRP Technique -- 4.2. Grafting of Polar Monomer from Polyolefin by Surface Activation -- 4.3. Direct Polymerization of Olefin with PolarMonomer though CRP Technique -- 4.4. Direct Radical Polymerization of Olefin with Polar Monomer -- 5. MACROMOLECULAR ARCHITECTURESOF POLYMER PRODUCED BY CRP -- Topology -- Compositions -- Functionality -- 6. APPLICATIONS -- 7. FUTURE PERSPECTIVE -- REFERENCES -- CHAPTER 7. THERMAL REDOX AND PHOTOINDUCED RING OPENING POLYMERIZATION REACTIONS: INITIATING SYSTEMS BASED ON ORGANOSILANES BEARING SI-SI BOND -- ABSTRACT -- INTRODUCTION -- THE CHEMICAL SYSTEMS AND POLYMERIZATION PROCEDURES -- I) Free Radical Photopolymerization (FRP) -- II) Free Radical Promoted Cationic Photopolymerization (FRPCP).

III) Redox Initiating Systems at RT -- 1. Backgrounds: The Organosilanes in FRP -- 1. A. Excited States and Radical Properties -- 1.B. The Photoinitiating Ability -- 1. C. Initiating Mechanism in FRP -- 2. The Photoinitiating Ability of the PI/Ph2I+ Combinations for FRPCP -- 3. The Redox Initiating Systems at RT -- 4. Formation of Nanoparticles in an Acrylate Matrix -- CONCLUSION -- REFERENCES -- INDEX.

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