TY  - BOOK
AU  - Mezhikovskii,S.M.
AU  - Arinstein,A.E.
AU  - Deberdeev,R.Ya
TI  - Oligomeric State of Substances
T2  - Polymer Science and Technology
SN  - 9781617285547
AV  - QD382.O43 -- M494 2009eb 
U1  - 547/.7 
PY  - 2009///
CY  - Hauppauge
PB  - Nova Science Publishers, Incorporated
KW  - Oligomers -- Structure
KW  - Electronic books
N1  - Intro -- OLIGOMERIC STATE OF SUBSTANCES -- OLIGOMERIC STATE OF SUBSTANCES -- CONTENTS -- OLIGOMERIC STATE OF SUBSTANCES -- PREFACE OF EDITOR -- PREFACE -- PREFACE BY AUTHORS -- INTRODUCTION -- REFERENCES -- Part 1    OLIGOMERS AS THE OBJECT OF RESEARCH: BASIC PRINCIPLES -- ABSTRACT -- 1.1. TERMINOLOGY, CONCEPTS AND DEFINITIONS -- 1.1.1. Briefly on The Subject -- 1.1.2. Meaning of Term "Oligomer" -- 1.1.3. Development of "Oligomer" Term Formulations -- 1.1.4. Oligomeric System as Statistical Ensemble -- 1.2. CLASSIFICATION PRINCIPLES OF OLIGOMER SYSTEMS -- 1.2.1. Taxonomy of Oligomers -- 1. According to the Ability of Oligomers to Take or Not to Take Part in Chemical Reactions -- 2. According to Chemical Nature of Oligomeric Blocks -- 3. According to the Chemical Nature of Functional Groups -- 4. According to Functionality Parameters -- 5. According to Curing Pattern -- 6. According to Topological Structure of the Cured Products -- 7. According to Relaxation State of the Cured Products -- 8. According to Preliminary Expertise -- 1.2.2. Taxonomy of Oligomers Introduced by A. Berlin -- 1.2.3. Taxonomy of Oligomer Blends -- Oligomer - Monomer Blends -- Oligomer - Oligomer Blends -- Oligomer - Polymer Blends -- Compatibility of Components -- 1.3. STRUCTURAL ORGANIZATION OF OLIGOMER BLENDS -- 1.3.1. Structural Hierarchy -- Molecular Level -- Supramolecular Level -- Topological Level -- Colloidal Level -- Geometric Features -- Thermodynamic Features -- Kinetic Features -- 1.4. SOME THERMODYNAMIC CHARACTERISTICS OF OLIGOMER SYSTEMS -- 1.4.1. Thermodynamic Aspect -- 1.4.2. Kinetic Aspect -- 1.4.3. Methodological Aspect -- 1.4.4. Colloidal Aspect -- 1.4.5. Compatibility and Phase Equilibrium -- CONCLUSION -- REFERENCES -- Part 2    HOMOGENEOUS OLIGOMER SYSTEMS -- ABSTRACT -- 2.1. MOLECULAR HETEROGENEITY OF OLIGOMERS; 2.1.1. Molecular Weight Distribution Functions -- 2.1.2. Functional Type Distribution -- 2.1.3. Critical Chromatography of Oligomers -- 2.2. SMALL SCALE OLIGOMER STRUCTURE: THEORETICAL ASPECTS -- 2.2.1. Small Scale Structure of Limited Length Chain with Finite Bending Rigidity (Scaling Estimations) -- 2.2.2. Oligomer Chain Statistics Depending on Length, Interlink Rigidity and Temperature -- 2.2.3. Orientational Ordering of Oligomer Molecules: Influence of Environment -- 2.2.4. Free Energy of Oligomer Molecules -- 2.3. SUPRAMOLECULAR STRUCTURE OF OLIGOMERS -- 2.3.1. Geometric Image of Oligomer Supramolecular Structure -- 2.3.2. Short Range Order -- 2.3.3. Terminology -- 2.3.4. Associative-Cybotactic Schematics of Oligomer Liquid Supramolecular Structure -- 2.4. THEORETICAL MODELS OF SUPRAMOLECULAR STRUCTURE FORMATION -- 2.4.1. Activation Model -- 2.4.2. Relaxation Model -- 2.4.3. Activation-Relaxation Model -- 2.4.4. Kinetic Model -- 2.4.5. Liquid Drop Model -- 2.5. LIFETIMES OF SHORT RANGE ORDERING -- 2.6. EXPERIMENTAL EXAMINATION OF OLIGOMER SUPRAMOLECULAR STRUCTURE -- 2.6.1. Analysis of Structure Components Distribution Function -- 2.6.2. Radiographic and Electron Microscope Examination -- 2.6.3. Thermodynamic Estimations -- 2.6.4. Orientation Phenomena -- 2.6.5. Computer Simulation -- 2.7. KINETICS OF EQUILIBRIUM SUPRAMOLECULAR STRUCTURE FORMATION IN HOMOGENEOUS OLIGOMER SYSTEMS -- 2.7.1. NMR Data on Relaxation to Equilibrium:Experiment and Theory -- 2.8. SUPRAMOLECULAR STRUCTURE OF OLIGOMERS AND SOME EXPERIMENTAL "ANOMALIES" OF THEIR MACROSCOPIC PROPERTIES -- 2.8.1. Curing Kinetics of Oligomers in its Initial Stage -- Anisotropy in Local Orders -- Background of Problem -- Anisotropy of Local Orders as the Factor Defining Initial Cure Velocity of Reactive Oligomeric Systems; Initial Curing Velocity as Thermodynamic Equilibration Test in Oligomer Systems -- 2.8.2. Rheological Properties of Oligomeric Systems -- Rheological Properties Dependence on Deformative and Time-Temperature Prehistory of Oligomeric Systems -- Relaxation to Equilibrium According to Rheological Tests Data -- Comparison of Rheological Experiment and Theory -- Thermal Hysteresis of Viscosity -- Rheology of Polymer-Oligomer Mixtures (Region of Small Oligomer Additions) -- 2.8.4. Oligomer Diffusion Characteristics -- CONCLUSION -- REFERENCES -- Part 3    HETEROGENEOUS OLIGOMER SYSTEMS -- ABSTRACT -- 3.1. BASIC PRINCIPLES OF PHASE SEPARATION -- 3.2. EXPERIMENTAL INVESTIGATION OF PHASE EQUILIBRIUM -- 3.2.1. Phase Transitions in Single-Component Systems -- 3.2.2. Phase State Diagrams of Binary Systems -- 3.2.3. Mixing of Oligomer Blends: Analysis of Thermodynamic Parameters -- Mixing Thermodynamics of Rubber - Oligoester Acrylates Systems -- Mixing Thermodynamics of PVC - Oligoester Acrylates Systems -- Mixing Thermodynamics of Oligobutadiene Urethane(met- ) Acrylate - Oligoester Acrylate Systems -- Temperature Dependencies -- Semidiluted Solutions -- Enthalpy -- Entropy -- Chemical Potential -- Diluted Solutions -- Enthalpy -- Entropy -- Chemical Potential -- Concentration Dependencies -- Thermodynamic Parameters as Related to UCST -- Mixing Thermodynamics of Oligoalkyleneglycoles Oligoethyleneglycoladipinate Systems -- Invariance of Phase Diagrams and Thermodynamic Parameters -- 3.3. FORMATION OF EQUILIBRIUM STRUCTURE IN HETEROGENEOUS OLIGOMER BLENDS -- 3.4. EXPERIMENTAL EXAMINATION OF MACROSCOPIC PROPERTIES -- 3.4.1. Features of Rotational Diffusion -- 3.4.2. Features of Translational Diffusion -- 3.4.3. Specific Aspects of Viscous Flow -- Phase Transition Area -- Viscosity in Critical Point and in Metastable Area -- Viscosity of Heterogeneous Systems; 3.4.4. Effect of Phase Structure on Initial Curing Rate -- 3.4.5. The Relative Effect of Thermodynamic and Kinetic Factors on Bulk Properties and Formation of an Equilibrium Oligomer Structure -- CONCLUSION -- REFERENCES -- CONCLUSION -- REFERENCES -- INDEX -- Blank Page
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