Baumgartner, Thomas.

Main Group Strategies Towards Functional Hybrid Materials. - 1st ed. - 1 online resource (786 pages)

Intro -- Title Page -- Table of Contents -- List of Contributors -- Preface -- 1 Incorporation of Boron into π‐Conjugated Scaffolds to Produce Electron‐Accepting π‐Electron Systems -- 1.1 Introduction -- 1.2 Boron‐Containing Five‐Membered Rings: Boroles and Dibenzoboroles -- 1.3 Annulated Boroles -- 1.4 Boron‐Containing Seven‐Membered Rings: Borepins -- 1.5 Boron‐Containing Six‐Membered Rings: Diborins -- 1.6 Planarized Triphenylboranes and Boron‐Doped Nanographenes -- 1.7 Conclusion and Outlook -- References -- 2 Organoborane Donor-Acceptor Materials -- 2.1 Organoboranes: Form and Functions -- 2.2 Linear D‐A Systems -- 2.3 Non‐conjugated D‐A Organoboranes -- 2.4 Conjugated Nonlinear D‐A Systems -- 2.5 Polymeric Systems -- 2.6 Cyclic D‐A Systems: Macrocycles and Fused‐Rings -- 2.7 Conclusions and Outlook -- References -- 3 Photoresponsive Organoboron Systems -- 3.1 Introduction -- 3.2 Photoreactivity of (ppy)BMes2 and Related Compounds -- 3.3 Photoreactivity of BN‐Heterocycles -- 3.4 New Photochromism of BN‐Heterocycles -- 3.5 Exciton Driven Elimination (EDE): In situ Fabrication of OLEDs -- 3.6 Summary and Future Prospects -- References -- 4 Incorporation of Group 13 Elements into Polymers -- 4.1 Introduction -- 4.2 Tricoordinate Boron in Conjugated Polymers -- 4.3 Tetracoordinate Boron Chelate Complexes in Polymeric Materials -- 4.4 Polymeric Materials with B‐P and B‐N in the Backbone -- 4.5 Polymeric Materials Containing Borane and Carborane Clusters -- 4.6 Polymeric Materials Containing Higher Group 13 Elements -- 4.7 Conclusions -- Acknowledgements -- References -- 5 Tetracoordinate Boron Materials for Biological Imaging -- 5.1 Introduction -- 5.2 Small Molecule Fluorescence Imaging Agents -- 5.3 Polymer Conjugated Materials -- 5.4 Conclusion and Future Outlook -- References -- 6 Advances and Properties of Silanol‐Based Materials. 6.1 Introduction -- 6.2 Preparation -- 6.3 Reactivity -- 6.4 Properties and Application -- References -- 7 Silole‐Based Materials in Optoelectronics and Sensing -- 7.1 Introduction -- 7.2 Basic Aspects of Silole‐Based Materials -- 7.3 Silole‐Based Electron‐Transporting Materials -- 7.4 Silole‐Based Host and Hole‐Blocking Materials for OLEDs -- 7.5 Silole‐Based Light‐Emitting Materials -- 7.6 Silole‐Based Semiconducting Materials -- 7.7 Silole‐Based Light‐Harvesting Materials for Solar Cells -- 7.8 Silole‐Based Sensing Materials -- 7.9 Conclusion -- References -- 8 Materials Containing Homocatenated Polysilanes -- 8.1 Introduction -- 8.2 Synthesis -- 8.3 Functional Modification of Polysilanes -- 8.4 Control of the Stereochemistry of Polysilanes -- 8.5 Control of the Secondary Structure of Polysilanes -- 8.6 Polysilanes with 3D Architectures -- 8.7 Applications -- 8.8 Summary -- References -- 9 Catenated Germanium and Tin Oligomers and Polymers -- 9.1 Introduction -- 9.2 Oligogermanes and Oligostannanes -- 9.3 Preparation of Polygermanes -- 9.4 Preparation of Polystannanes -- 9.5 Conclusions and Outlook -- Acknowledgements -- References -- 10 Germanium and Tin in Conjugated Organic Materials -- 10.1 Introduction -- 10.2 Germanium and Tin‐Linked Conjugated Polymers -- 10.3 Germanium‐ and Tin‐Containing Conjugated Cyclic Systems -- 10.4 Summary and Outlook -- References -- 11 Phosphorus‐Based Porphyrins -- 11.1 Introduction -- 11.2 Porphyrins Bearing Phosphorus‐Based Functional Groups at their Periphery -- 11.3 Porphyrins and Related Macrocycles Containing Phosphorus Atoms at their Core -- 11.4 Conclusions -- Acknowledgements -- References -- 12 Applications of Phosphorus‐Based Materials in Optoelectronics -- 12.1 Introduction -- 12.2 Phosphines -- 12.3 Four‐Membered P‐Heterocyclic Rings -- 12.4 Five‐Membered P‐Heterocyclic Rings: Phospholes. 12.5 Six‐Membered P‐Heterocyclic Rings -- 12.6 Conclusion -- Abbreviations -- References -- 13 Main‐Chain, Phosphorus‐Based Polymers -- 13.1 Introduction -- 13.2 Polyphosphazenes -- 13.3 Poly(phosphole)s -- 13.4 Poly(methylenephosphine)s -- 13.5 Poly(arylene‐/vinylene‐/ethynylene‐phosphine)s -- 13.6 Phospha‐PPVs -- 13.7 Poly(phosphinoborane)s -- 13.8 Metal‐Containing Phosphorus Polymers -- 13.9 Additional P‐Containing Polymers -- 13.10 Summary -- Acknowledgements -- References -- 14 Synthons for the Development of New Organophosphorus Functional Materials -- 14.1 General Introduction -- 14.2 Phosphorus Transfer Reagents as Emerging Synthetic Approaches to Materials -- 14.3 Carbene‐Stabilized Molecules as Phosphorus Reagents -- 14.4 Conclusions and Outlook -- References -- 15 Arsenic‐Containing Oligomers and Polymers -- 15.1 Introduction -- 15.2 Chemistry of Organoarsenic Compounds -- 15.3 Arsenic Homocycles -- 15.4 Development of C-As Bond Formation for Organoarsenic Compounds -- 15.5 Properties of Poly(vinylene‐arsine)s -- 15.6 Properties of 1,4‐Dihydro‐1,4‐diarsinines -- 15.7 Properties of Arsole Derivatives -- 15.8 Arsole‐Containing Polymers -- 15.9 Conclusions -- References -- 16 Antimony‐ and Bismuth‐Based Materials and Applications -- 16.1 Introduction -- 16.2 Anion Binding and Sensing Applications -- 16.3 Small‐Molecule Binding -- 16.4 Antimony and Bismuth Chromophores -- 16.5 Conclusion -- References -- 17 High Sulfur Content Organic/Inorganic Hybrid Polymeric Materials -- 17.1 Introduction -- 17.2 The Chemistry of Liquid Sulfur -- 17.3 Waterborne Reactions of Polysulfides -- 17.4 Controlled Polymerization with High Sulfur‐Content Monomers -- 17.5 Modern Applications of High Sulfur‐Content Copolymers -- 17.6 Conclusion and Outlook -- Acknowledgements -- References -- 18 Selenium and Tellurium Containing Conjugated Polymers. 18.1 Introduction -- 18.2 Selenium‐Containing Conjugated Polymers -- 18.3 Tellurium‐Containing Conjugated Polymers -- 18.4 Conclusions and Outlook -- References -- 19 Hypervalent Iodine Compounds in Polymer Science and Technology -- 19.1 Introduction -- 19.2 Applications of Hypervalent Iodine Compounds in Polymer Science and Technology -- 19.3 Conclusions -- Acknowledgements -- References -- Index -- End User License Agreement.

9781119235958


Composite materials.
Nanostructured materials.
Polymers.


Electronic books.

TA418.9.C6 .M356 2018

620.118