Tiwari, Ashutosh.
Advanced Molecularly Imprinting Materials.
- 1st ed.
- 1 online resource (723 pages)
- Advanced Material Series .
- Advanced Material Series .
Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Part 1 Strategies of Affinity Materials -- 1 Recent Molecularly Imprinted Polymer-based Methods for Sample Preparation -- 1.1 Introduction -- 1.2 Molecularly Imprinted Solid-phase Extraction -- 1.2.1 General Considerations -- 1.2.2 Online and Inline Protocols -- 1.2.3 Improved Batch Protocols -- 1.3 Molecularly Imprinted Solid-phase Microextraction -- 1.3.1 MIP-coated Fibers -- 1.3.2 MIP Fibers (Monoliths) -- 1.4 Molecularly Imprinted Stir Bar Sorptive Extraction -- 1.5 Other Formats -- 1.5.1 Matrix Solid-phase Dispersion -- 1.5.2 Liquid Membranes and MIPs Combination -- 1.6 Conclusions -- References -- 2 A Genuine Combination of Solvent-free Sample Preparation Technique and Molecularly Imprinted Nanomaterials -- 2.1 Introduction -- 2.1.1 The Overview -- 2.1.2 General Procedure for Solid-phase Microextraction and Their Basic Components -- 2.1.3 Some Recent Examples of Solid-phase Microextraction Technique and Their Reviews -- 2.1.4 Selectivity Problem: Introduction of Molecularly Imprinted Polymer (MIP) -- 2.2 Molecularly Imprinted Polymer Modified Fiber for Solid-phase Microextraction -- 2.2.1 MISPME Using Modified Silica fiber as Stationary Phase -- 2.2.2 MISPME Using Modified Metal Fiber as Stationary Phase -- 2.2.3 Other MISPME Fibers -- 2.3 In-tube Solid-phase Microextraction Technique -- 2.4 Monolithic Fiber -- 2.5 Micro-solid-phase Extraction -- 2.6 Stir-bar Sorptive Extraction -- 2.7 Conclusion and Future Scope -- Acknowledgments -- Abbreviations -- References -- 3 Fluorescent Molecularly Imprinted Polymers -- 3.1 Introduction -- 3.2 Classes of Emitters to Endow MIPs with Fluorescence -- 3.2.1 Fluorescent Dyes -- 3.2.1.1 Changes in the Local Environment Induced by Template Rebinding -- 3.2.1.2 Hydrogen-bonding Interactions Between Template and Fluorescent Dye. 3.2.1.3 Electrostatic Interactions Between Template and Fluorescent Dye -- 3.2.1.4 Coordinative Interactions Between Template and Fluorescent Dye -- 3.2.1.5 Covalent Bonds Between Template and Fluorescent Dye -- 3.2.2 Fluorescent Probes -- 3.2.3 Lanthanide-based Systems -- 3.2.4 Quantum Dots -- 3.2.5 Carbon Dots -- 3.2.6 Upconversion Nanoparticles -- 3.3 Fluorescent Molecularly Imprinted Silica -- 3.4 Post-imprinting of MIPs -- 3.5 fMIPs as Labels -- 3.6 Formats for fMIPs -- 3.6.1 Bulk fMIPs -- 3.6.2 fMIP Films -- 3.6.3 fMIPs-containing Micro- and Nanoparticles -- 3.7 Conclusion -- References -- 4 Molecularly Imprinted Polymer-based Micro- and Nanotraps for Solid-phase Extraction -- 4.1 Introduction -- 4.2 MIPs as SPE Materials -- 4.2.1 MIP-based SPE for Environmental Samples -- 4.2.2 MIP-based SPE for Biological Samples -- 4.2.3 MIP-based SPE for Food and Beverage Samples -- 4.3 Conclusions -- References -- 5 Imprinted Carbonaceous Nanomaterials: A Tiny Looking Big Thing in the Field of Selective and Specific Analysis -- 5.1 Introduction -- 5.1.1 Popularly Used Carbon-based Nanomaterials -- 5.1.1.1 Graphene -- 5.1.1.2 Carbon Nanotubes -- 5.1.1.3 Graphene Quantum Dots/Carbon Nanodots -- 5.1.1.4 Problems in Their Use -- 5.1.2 Introduction of Molecularly Imprinted Polymers as a Selectivity Factor -- 5.1.3 Combination of MIPs and Carbonaceous Nanomaterials: Solution for Each Other -- 5.2 Graphene-modified Imprinted Polymer -- 5.2.1 Graphene-modified Imprinted Polymer in Combination with Nanoparticle -- 5.3 Carbon Nanotubes-modified Imprinted Polymer -- 5.4 Combination of Graphene, CNTs, and MIPs -- 5.5 Graphene Quantum Dots and/or Carbon Dots -- 5.6 Fullerene -- 5.7 Activated Carbon -- 5.8 Conclusions -- Acknowledgments -- List of Abbreviations -- References -- 6 Molecularly Imprinted Materials for Fiber-optic Sensor Platforms -- 6.1 Introduction. 6.1.1 General Information -- 6.1.2 General Principle of Molecular Imprinting Materials -- 6.1.2.1 Characterization of Molecularly Imprinted Polymers -- 6.1.3 General Detection Principle and Molecular Aspect of MIPs for FO Sensors -- 6.2 Material Aspect: Morphology and Physical Forms of MIPs in FO Sensors -- 6.2.1 Morphology -- 6.2.2 Physical Forms -- 6.2.2.1 Microsphere -- 6.2.2.2 Nanoparticles -- 6.2.2.3 MIPs Layers/Thin Films -- 6.3 Molecularly Imprinting Technology for Fiber-optic Sensors -- 6.3.1 General Principle of Fiber-optic Sensing -- 6.3.1.1 Extrinsic Sensing -- 6.3.1.2 Intrinsic Sensing -- 6.3.1.3 Application Areas -- 6.3.2 Sensing Functionalities and Mechanisms of Current FO Sensors -- 6.3.2.1 Fluorescence-based FOs -- 6.3.2.2 Absorption-based FOs -- 6.3.2.3 Reflectance-based FOs -- 6.3.2.4 Resonance-based Sensors -- 6.3.2.5 Classification Based on Modulation Types -- 6.3.3 Design of MIPs for Fiber-optic Sensors -- 6.3.3.1 Design Process of MIPs -- 6.3.3.2 Development and Optimization of MIPs -- 6.3.3.3 Synthesis of MIPs -- 6.3.4 Characterization Methods for MIPs -- 6.3.4.1 Chemical Characterization -- 6.3.4.2 Morphological Characterization -- 6.3.4.3 Binding Behavior Characterization -- 6.4 State-of-the-art Fiber-optic Sensors Applications Using Molecularly Imprinted Materials -- 6.5 Conclusion -- References -- Part 2 Rational Design of MIP for Advanced Applications -- 7 Molecularly Imprinted Polymer-based Sensors for Biomedical and Environmental Applications -- 7.1 Introduction -- 7.1.1 General Aspects of Molecularly Imprinting Technology -- 7.1.2 Synthesis Strategies for MIPs -- 7.1.3 MIP Polymerization Strategies -- 7.1.4 Molecular Imprinted Polymer Bonding Techniques -- 7.1.4.1 Covalent Bond Method (Pre-assembly Method) -- 7.1.4.2 Noncovalent Method (Self-assembly Method) -- 7.1.4.3 Semicovalent Imprinting. 7.1.4.4 Imprinting via Metal Coordination -- 7.1.4.5 Combinatorial Imprinting -- 7.1.5 Detection Methods for Molecularly Imprinted Polymer-based Sensors -- 7.1.5.1 Optical Detection Methods -- 7.1.5.2 Piezoelectrical Detection Methods -- 7.1.5.3 Electrochemical Detection Methods -- 7.2 Molecularly Imprinted Polymers for Analytes of Biomedical Interest -- 7.2.1 Motivation and Interest of Developing Molecularly Imprinted Polymers in the Biomedical Filed -- 7.2.2 The Pretreatment of Biological Samples When Using Molecularly Imprinted Polymer-based Sensors -- 7.2.3 Electrochemical Sensors Based on Molecularly Imprinted Polymers -- 7.2.4 Massic Sensors Based on Molecularly Imprinted Polymers -- 7.2.5 Optical Sensors Based on Molecularly Imprinted Polymers -- 7.3 Molecularly Imprinted Polymers for Analytes of Environmental Interest -- 7.3.1 Pesticides -- 7.3.2 Explosives and Warfare Agents -- 7.4 Conclusion -- Acknowledgments -- References -- 8 Molecularly Imprinted Polymers: The Affinity Adsorbents for Environmental Biotechnology -- 8.1 Introduction -- 8.2 Molecularly Imprinted Polymers -- 8.2.1 Monomers -- 8.2.2 Cross-linking Agents -- 8.2.3 Mode of Polymerization -- 8.3 Cryogels -- 8.4 Process Technology -- 8.5 Applications -- 8.5.1 Example: Capture of Compounds Binding to Estrogen Receptors -- 8.5.2 Example: Capture of Pesticides -- 8.5.3 Example: Capture of Pharmaceuticals and Their Metabolites -- 8.5.4 Example: Capture of Heavy-metal Ions -- 8.6 Elution of Captured Material -- 8.6.1 Example: MIPs as Sensing Elements in Environmental Monitoring -- 8.7 Concluding Remarks -- 8.8 Outlook -- References -- 9 Molecular Imprinting Technology for Sensing and Separation in Food Safety -- 9.1 Food Safety -- 9.2 Food Analysis -- 9.3 Current Separation Methods Used for Food Safety Purposes -- 9.4 What Is MIP? -- 9.5 MIP Applications Used for Food Safety Purposes. 9.5.1 Contaminants -- 9.5.1.1 Mycotoxins -- 9.5.1.2 Color Compounds -- 9.5.1.3 Pesticide Residues -- 9.5.1.4 Antibiotics -- 9.5.1.5 Vitamins -- 9.5.1.6 Hormones -- References -- 10 Advanced Imprinted Materials for Virus Monitoring -- 10.1 Introduction -- 10.2 Virus Imprinting -- 10.3 Artificial MIP Receptors for Viruses -- 10.4 Virus Monitoring and Detection Using Biomimetic Sensors -- 10.5 Virus Imprinting for Separation Technologies -- 10.6 Conclusions -- References -- 11 Design and Evaluation of Molecularly Imprinted Polymers as Drug Delivery Systems -- 11.1 Introduction -- 11.1.1 Drug Delivery Systems -- 11.1.2 Polymers for DDS -- 11.2 Synthesis and Characterization of MIPs Intended for Drug Release Using Non-covalent Approaches -- 11.2.1 Precipitation Polymerization -- 11.2.2 Characterization Studies -- 11.3 Design and Evaluation of Drug Delivery Systems Based on MIPs -- 11.3.1 Release Studies -- 11.3.2 Mathematical Modeling -- 11.4 Conclusions -- References -- 12 Molecularly Imprinted Materials for Controlled Release Systems -- 12.1 Introduction -- 12.2 Selectivity, Release Mechanism and Functionality of MIPs-based CR Systems -- 12.2.1 Factors That Influence the Selectivity -- 12.2.2 Recognition Characteristics of MIPs -- 12.2.2.1 Binding Site Heterogeneity -- 12.2.2.2 Restrictions on Recognition Characteristics of MIPs -- 12.2.3 Sustained-release MIP Drug Delivery Systems -- 12.2.3.1 Drug Delivery Based on Rate-programming -- 12.2.3.2 Drug Delivery Based on Activation-modulation -- 12.2.3.3 Feedback-regulated DDS -- 12.3 Molecularly Imprinted Polymers Production for Controlled Release -- 12.3.1 Synthesis and Characterization of Molecularly Imprinted Polymers -- 12.3.1.1 Synthesis Methods -- 12.3.1.2 Characterization of MIPs -- 12.3.2 Recognition Mechanisms and Types of Monomer/Template Interactions -- 12.3.2.1 Mechanism of Recognition. 12.3.2.2 Types of Monomer/Template Interactions.
9781119336167
Molecular Imprinting.
Electronic books.
TP156.P6A383 2017
668.92