Introduction to Molecular Magnetism : From Transition Metals to Lanthanides.

Cover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 Introduction -- 1.1 A Nano History of Molecular Magnetism -- 1.2 Molecules, Conductors, and Magnets -- 1.3 Origin of Molecular Magnetism -- 1.4 Playing with the Periodic Table -- 1.5 p Magnetic Orbitals -- 1.6 d Magnetic Orbitals -- 1.7 f Magnetic Orbitals -- 1.8 The Goals of Molecular Magnetism -- 1.9 Why a Book -- 1.10 Outlook -- 1.11 The Applications of Ln -- 1.12 Finally SI versus emu -- References -- Chapter 2 Electronic Structures of Free Ions -- 2.1 The Naked Ions -- 2.2 Spin-Orbit Coupling -- 2.3 Applying a Magnetic Field -- References -- Chapter 3 Electronic Structure of Coordinated Ions -- 3.1 Dressing Ions -- 3.2 The Crystal Field -- 3.3 The aquo Ions -- 3.4 The Angular Overlap Model -- 3.5 The Lantanum(III) with Phthalocyanine (Pc) and PolyOxoMetalates (POM) -- 3.6 Introducing Magnetic Anisotropy -- References -- Chapter 4 Coordination Chemistry and Molecular Magnetism -- 4.1 Introduction -- 4.2 Pyrazolylborates -- 4.3 Phthalocyanines -- 4.4 Cyclopentadiene and Cyclooctatetraene -- 4.5 Polyoxometalates (POMs) -- 4.6 Diketonates -- 4.7 Nitronyl-nitroxides (NITs) -- 4.8 Carboxylates -- 4.9 Schiff Bases -- References -- Chapter 5 Magnetism of Ions -- 5.1 The Curie Law -- 5.2 The Van Vleck Equation -- 5.3 Anisotropy Steps in -- References -- Chapter 6 Molecular Orbital of Isolated Magnetic Centers -- 6.1 Moving to MO -- 6.2 Correlation Effects -- 6.3 DFT -- 6.4 The Complexity of Simple -- 6.5 DFT and Single Ions -- 6.6 DOTA Complexes, Not Only Contrast -- References -- Chapter 7 Toward the Molecular Ferromagnet -- 7.1 Introduction -- 7.2 A Road to Infinite -- 7.3 Magnetic Interactions -- 7.4 Introducing Interactions: Dipolar -- 7.5 Spin Hamiltonians -- 7.6 The Giant Spin -- 7.7 Single Building Block -- 7.8 Multicenter Interactions -- 7.9 Noncollinearity.

7.10 Introducing Orbital Degeneracy -- References -- Chapter 8 Molecular Orbital of Coupled Systems -- 8.1 Exchange and Superexchange -- 8.2 Structure and Magnetic Correlations: d Orbitals -- 8.3 Quantum Chemical Calculations of SH Parameters -- 8.4 Copper Acetate! -- 8.5 Mixed Pairs: Degenerate-Nondegenerate -- 8.6 f Orbitals and Orbital Degeneracy -- References -- Chapter 9 Structure and Properties of p Magnetic Orbitals Systems -- 9.1 Magnetic Coupling in Organics -- 9.2 Magnetism in Nitroxides -- 9.3 Thioradicals -- 9.4 Metallorganic Magnets -- 9.5 Semiquinone Radicals -- 9.6 NITR Radicals with Metals -- 9.7 Long Distance Interactions in Nitroxides -- References -- Chapter 10 Structure and Properties of Coupled Systems: d, f -- 10.1 d Orbitals -- 10.2 3d -- 10.3 4d and 5d -- 10.4 Introducing Chirality -- 10.5 f-d Interactions -- 10.6 A Model DFT Calculation -- 10.7 Magneto-Structural Correlations in Gd-Cu -- 10.8 f Orbital Systems and Orbital Degeneracy -- References -- Chapter 11 Dynamic Properties -- 11.1 Introductory Remarks -- 11.2 Spin-Lattice Relaxation and T1 -- 11.3 Phonons and Direct Mechanism -- 11.4 Two Is Better than One -- 11.5 Playing with Fields -- 11.6 Something Real -- 11.7 Spin-Spin Relaxation and T2 -- References -- Chapter 12 SMM Past and Present -- 12.1 Mn12, the Start -- 12.2 Some Basic Magnetism -- 12.3 Fe4 Structure and Magnetic Properties -- 12.4 Fe4 Relaxation and Quantum Tunneling -- 12.5 And τ0? -- 12.6 Deep in the Tunnel -- 12.7 Magnetic Dilution Effects -- 12.8 Single Molecule Magnetism -- References -- Chapter 13 Single Ion Magnet (SIM) -- 13.1 Why Single -- 13.2 Slow Relaxation in Ho in Inorganic Lattice -- 13.3 Quantum Tunneling of the Magnetization: the Role of Nuclei -- 13.4 Back to Magnets -- 13.5 The Phthalocyanine Family: Some More Chemistry -- 13.6 The Anionic Double Decker -- 13.7 CF Aspects.

13.8 The Breakthrough -- 13.9 Multiple Deckers -- 13.10 The Polyoxometalate Family -- 13.11 More SIM -- 13.12 Perspectives -- References -- Chapter 14 SMM with Lanthanides -- 14.1 SMM with Lanthanides -- 14.2 More Details on SMM with Lanthanides -- 14.3 New Opportunities -- References -- Chapter 15 Single Chain Magnets (SCM) and More -- 15.1 Why 1D -- 15.2 The Glauber Model -- 15.3 SCM: the d and p Way -- 15.4 Spin Glass -- 15.5 Noncollinear One-dimensional Systems -- 15.6 f Orbitals in Chains: Gd -- 15.7 f Orbitals in Chains: Dy -- 15.8 Back to Family -- References -- Chapter 16 Magic Dysprosium -- 16.1 Exploring Single Crystals -- 16.2 The Role of Excited States -- 16.3 A Comparative Look -- 16.4 Dy as a Perturbation -- References -- Chapter 17 Molecular Spintronics -- 17.1 What? -- 17.2 Molecules and Mobile Electrons -- 17.3 Of Molecules and Surfaces -- 17.4 Choosing Molecules and Surfaces -- 17.5 Is it Clean? -- 17.6 X-Rays for Magnetism -- 17.7 Measuring Magnetism on Surfaces -- 17.8 Transport through Single Radicals -- 17.9 Pc Family -- 17.10 Mn12 Forever -- 17.11 Hybrid Organic and f Orbitals -- 17.12 Magnetically Active Substrates -- 17.13 Using Nuclei -- 17.14 Some Device at Last -- References -- Chapter 18 Hunting for Quantum Effects -- 18.1 From Classic to Quantum -- 18.2 Basic QIP -- 18.3 A Detour -- 18.4 Endohedral Fullerenes -- 18.5 Criteria for QIP -- 18.6 Starting from Inorganic -- 18.7 Molecular Rings -- 18.8 V15 -- 18.9 Qubit Manipulation -- 18.10 Some Philosophy -- References -- Chapter 19 Controlling the Growth -- 19.1 Introduction -- 19.2 Metal-Organic Frameworks MOFs -- 19.3 From Nano to Giant -- 19.4 Molybdates -- 19.5 To the Limit -- 19.6 Controlling Anisotropy -- 19.7 Cluster with Few Lanthanides -- 19.8 Analyzing the Magnetic Properties -- 19.9 Two-Dimensional Structures -- References -- Chapter 20 ESR.

20.1 A Bird's Eye View of ESR of Ln -- 20.2 Gd in Detail -- 20.3 Gd with Radicals -- 20.4 Including Orbit -- 20.5 Involving TM -- 20.6 Ln Nicotinates -- 20.7 Measuring Distances -- References -- Chapter 21 NMR -- 21.1 NMR of Rare Earth Nuclides -- 21.2 NMR of Lanthanide Ions in Solution -- 21.3 Lanthanide Shift Reagents (LSR) -- References -- Chapter 22 Magnetic Resonance Imaging -- 22.1 Chemical Exchange Saturation Transfer (CEST) -- References -- Chapter 23 Some Applications of MM -- 23.1 Magnetocaloric Effect -- 23.2 Luminescence -- 23.2.1 Electroluminescent Materials for OLED -- 23.2.2 Biological Assays and Medical Imaging -- References -- Appendix A -- Appendix B -- Index -- EULA.

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Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2024. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.