Materials Kinetics Fundamentals.

Cover -- Title Page -- Copyright -- Contents -- Preface -- Acknowledgments -- Learning Objectives -- Part I Kinetic Principles -- Chapter 1 Introduction to Materials Kinetics -- 1.1 What Is Kinetics? -- 1.2 Kinetics Versus Thermodynamics -- 1.3 Homogeneous Versus Heterogeneous Kinetics -- 1.4 Reaction Versus Diffusion -- 1.5 Classifying Kinetic Processes -- 1.6 Brief Word about Units -- 1.7 Chapter Summary -- 1.8 Chapter Exercises -- Chapter 2 A Short Detour into Thermodynamics -- 2.1 Dynamic Equilibrium -- 2.2 Enthalpy (H), Entropy (S), and Gibbs Free Energy (G) -- 2.2.1 Relationship between ΔG, ΔH, and ΔS -- 2.3 Molar Quantities -- 2.4 Standard State -- 2.5 Calculating Thermodynamic Quantities -- 2.6 Reaction Quotient Q and Equilibrium Constant K -- 2.7 Temperature Dependence of K -- 2.8 Thermodynamics of Phase Transformations -- 2.9 Ideal Gas Law -- 2.10 Calculating Concentrations for Liquids or Solids -- 2.10.1 Calculating Densities/Concentrations in Pure Materials -- 2.10.2 Calculating Densities/Concentrations in Stoichiometric Compounds or Dilute Solutions -- 2.10.3 Calculating Densities/Concentrations for Mixtures of Multiple Phases/Compounds -- 2.10.4 Calculating Densities/Concentrations from Crystallographic Information -- 2.10.5 Calculating Site Fractions -- 2.11 Chapter Summary -- 2.12 Chapter Exercises -- Chapter 3 Chemical Reaction Kinetics -- 3.1 Homogeneous versus Heterogeneous Chemical Reactions -- 3.2 Homogeneous Chemical Reactions -- 3.2.1 Reaction Rate Equation and k -- 3.2.2 Order of Reaction -- 3.2.3 Zero-Order Reactions -- 3.2.4 First-Order Reactions -- 3.2.5 Second-Order Reactions -- 3.2.6 Incomplete Reactions/Equilibrium Reactions -- 3.2.7 Summary of Homogeneous Reaction Kinetics -- 3.3 Temperature Dependence of Reaction Kinetics: Activation Theory -- 3.4 Heterogeneous Chemical Reactions -- 3.4.1 Effect of Catalyst.

3.4.2 Gas-Solid Surface Reaction Processes -- 3.5 Chapter Summary -- 3.6 Chapter Exercises -- Chapter 4 Transport Kinetics (Diffusion) -- 4.1 Flux -- 4.2 Fluxes and Forces -- 4.3 Common Transport Modes (Force/Flux Pairs) -- 4.4 Phenomenological Treatment of Diffusion -- 4.4.1 Steady-State Diffusion: Fick's First Law -- 4.4.2 Transient Diffusion: Fick's Second Law -- 4.4.3 Kirkendal Effect and Moving Interface Problems -- 4.4.4 Summary of Transient Diffusion Problems -- 4.4.5 Coupled Diffusion Processes -- 4.5 Atomistic Treatment of Diffusion -- 4.5.1 Overview of Diffusion in Gases Versus Liquids Versus Solids -- 4.5.2 Diffusion in Gases: Kinetic Theory of Gases -- 4.5.3 Diffusion in Solids: Atomistic Mechanisms of Solid-State Diffusion -- 4.5.4 Diffusion in Solids: High-Diffusivity Paths -- 4.6 Chapter Summary -- 4.7 Chapter Exercises -- Part II Applications of Materials Kinetics -- Chapter 5 Gas-Solid Kinetic Processes -- 5.1 Adsorption/Desorption -- 5.2 Active Gas Corrosion -- 5.3 Chemical Vapor Deposition -- 5.4 Atomic Layer Deposition -- 5.5 Passive Oxidation -- 5.6 Chapter Summary -- 5.7 Chapter Exercises -- Chapter 6 Liquid-Solid and Solid-Solid Phase Transformations -- 6.1 What Is a Phase Transformation? -- 6.2 Driving Forces for Transformation: Temperature and Composition -- 6.2.1 Calculating ΔGV -- 6.3 Spinodal Decomposition: A Continuous Phase Transformation -- 6.4 Surfaces and Interfaces -- 6.4.1 Estimating Surface Energies -- 6.4.2 Interfacial Energy Balances -- 6.4.3 Overview of Important Surface/Interface Energy Effects -- 6.5 Nucleation -- 6.5.1 Homogeneous Nucleation -- 6.5.2 Heterogeneous Nucleation -- 6.5.3 Nucleation Rate -- 6.6 Growth -- 6.7 Nucleation and Growth Combined -- 6.7.1 Effect of Nucleation Rate versus Growth Rate on Microstructure -- 6.7.2 Overall Rate of Transformation: Johnson-Mehl and Avrami Equations.

6.7.3 Time-Temperature-Transformation Diagrams -- 6.8 Solidification -- 6.8.1 Casting Microstructures -- 6.8.2 Plane Front Solidification (Scheil Equation) -- 6.8.3 Cellular or Dendritic Growth -- 6.8.4 Eutectic Lamellae -- 6.8.5 Peritectic Solidification -- 6.9 Martensitic Transformations -- 6.10 Chapter Summary -- 6.11 Chapter Exercises -- Chapter 7 Microstructural Evolution -- 7.1 Capillary Forces -- 7.2 Surface Evolution -- 7.2.1 Surface Evolution by Solid-State Diffusion -- 7.2.2 Surface Evolution by Vapor-Phase Transport -- 7.3 Coarsening -- 7.3.1 Diffusion-Limited Coarsening -- 7.3.2 Source/Sink-Limited Coarsening -- 7.4 Grain Growth -- 7.5 Sintering -- 7.6 Chapter Summary -- 7.7 Chapter Exercises -- References -- Part III Appendixes -- Appendix A Units -- Appendix B Periodic Table -- Appendix C Answers to Selected Calculation Questions -- Index -- EULA.

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Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2024. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.