ORPP logo
Image from Google Jackets

Surfactant Science and Technology.

By: Material type: TextTextPublisher: Newark : John Wiley & Sons, Incorporated, 2020Copyright date: ©2020Edition: 4th edDescription: 1 online resource (419 pages)Content type:
  • text
Media type:
  • computer
Carrier type:
  • online resource
ISBN:
  • 9781119465843
Subject(s): Genre/Form: Additional physical formats: Print version:: Surfactant Science and TechnologyDDC classification:
  • 541/.33
LOC classification:
  • QD506 .M947 2020
Online resources:
Contents:
Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Chapter 1 An Overview of Surfactant Science and Technology -- 1.1 A Brief History of Surfactant Science and Technology -- 1.2 Surfactants in the Modern World -- 1.3 The Economics of Surfactant Science and Technology -- 1.4 The Near-Term Economic and Technological Future for Surfactants -- 1.5 Surfactants in the Environment -- 1.6 A Surfactant Glossary -- Chapter 2 The Classification of Surfactants -- 2.1 The Basic Structure of Amphiphilic Molecules -- 2.2 A Systematic Classification of Surfactants -- 2.2.1 Surfactant Solubilizing Groups -- 2.2.2 Making a Choice -- 2.3 The Generic Anatomy of Surfactants -- 2.3.1 The Many Faces of Dodecane -- 2.3.2 Surfactant Solubilizing Groups -- 2.3.3 Common Surfactant Hydrophobic Groups -- 2.3.3.1 The Natural Fatty Acids -- 2.3.3.2 Saturated Hydrocarbons or Paraffins -- 2.3.3.3 Olefins -- 2.3.3.4 Alkyl Benzenes -- 2.3.3.5 Alcohols -- 2.3.3.6 Alkyl Phenols -- 2.3.3.7 Polyoxypropylenes -- 2.3.3.8 Fluorocarbons -- 2.3.3.9 Silicone Surfactants -- 2.3.3.10 Miscellaneous Biological Structures -- 2.4 The Systematic Classification of Surfactants -- 2.5 Anionic Surfactants -- 2.5.1 Sulfate Esters -- 2.5.1.1 Fatty Alcohol Sulfates -- 2.5.1.2 Sulfated Fatty Acid Condensation Products -- 2.5.1.3 Sulfated Ethers -- 2.5.1.4 Sulfated Fats and Oils -- 2.5.2 Sulfonic Acid Salts -- 2.5.2.1 Aliphatic Sulfonates -- 2.5.2.2 Alkyl Aryl Sulfonates -- 2.5.2.3 α-Sulfocarboxylic Acids and Their Derivatives -- 2.5.2.4 Miscellaneous Sulfo-Ester and Amide Surfactants -- 2.5.2.5 Alkyl Glyceryl Ether Sulfonates -- 2.5.2.6 Lignin Sulfonates -- 2.5.3 Carboxylate Soaps and Detergents -- 2.5.4 Phosphoric Acid Esters and Related Surfactants -- 2.6 Cationic Surfactants -- 2.7 Nonionic Surfactants -- 2.7.1 Polyoxyethylene-Based Surfactants.
2.7.2 Derivatives of Polyglycerols and Other Polyols -- 2.7.3 Block Copolymer Nonionic Surfactants -- 2.7.4 Miscellaneous Nonionic Surfactants -- 2.8 Amphoteric Surfactants -- 2.8.1 Imidazoline Derivatives -- 2.8.2 Surface-Active Betaines and Sulfobetaines -- 2.8.3 Phosphatides and Related Amphoteric Surfactants -- Chapter 3 Surfactant Chemical Structures: Putting the Pieces Together -- 3.1 Surfactant Building Blocks -- 3.2 A Surfactant Family Tree -- 3.2.1 The Many Faces of Dodecane -- 3.3 Common Surfactant Hydrophobic Groups -- 3.3.1 The Natural Fatty Acids -- 3.3.2 Paraffins or Saturated Hydrocarbons -- 3.3.3 Olefins -- 3.3.4 Alkylbenzenes -- 3.3.5 Alcohols -- 3.3.6 Alkylphenols -- 3.3.7 Polyoxypropylene -- 3.3.8 Fluorocarbons -- 3.3.9 Silicone-Based Surfactants -- 3.3.10 Nonchemically Produced, a.k.a. "Natural" Surfactants -- Chapter 4 Natural Surfactants and Biosurfactants -- 4.1 What Makes a Surfactant "Natural"? -- 4.2 Surfactants Based on a Natural Sugar-Based Polar Head Groups -- 4.3 Biosurfactants -- 4.3.1 Biosurfactants as Nature Makes Them -- 4.3.2 Properties of Biosurfactants -- 4.3.3 Biosurfactant Classification -- 4.3.4 Some Aspects of Biosurfactant Production -- 4.3.5 Some Factors Affecting Biosurfactant Production -- 4.4 Biosurfactant Applications -- 4.5 Potential Limitations on the Commercial Use of Biosurfactants -- 4.6 Some Opportunities for Future Research and Development -- 4.7 Some Observations About the Future of Biosurfactants -- Chapter 5 Fluid Surfaces and Interfaces -- 5.1 Molecules at Interfaces -- 5.2 Interfaces and Adsorption Phenomena -- 5.2.1 A Thermodynamic Picture of Adsorption -- 5.2.2 Surface and Interfacial Tensions -- 5.2.3 The Effect of Surface Curvature -- 5.2.4 The Surface Tension of Solutions -- 5.2.5 Surfactants and the Reduction of Surface Tension.
5.2.6 Efficiency, Effectiveness, and Surfactant Structure -- Chapter 6 Surfactants in Solution: Self-Assembly and Micelle Formation -- 6.1 Surfactant Solubility -- 6.2 The Phase Spectrum of Surfactants in Solution -- 6.3 The History and Development of Micellar Theory -- 6.3.1 Manifestations of Micelle Formations -- 6.3.2 Thermodynamics of Dilute Surfactant Solutions -- 6.3.3 Classical Theories of Micelle Formation -- 6.3.4 Free Energy of Micellization -- 6.4 Molecular Geometry and the Formation of Association Colloids -- 6.5 Experimental Observations of Micellar Systems -- 6.5.1 Micellar Aggregation Numbers -- 6.5.2 The Critical Micelle Concentration -- 6.5.3 The Hydrophobic Group -- 6.5.4 The Hydrophilic Group -- 6.5.5 Counterion Effects on Micellization -- 6.5.6 The Effects of Additives on the Micellization Process -- 6.5.6.1 Electrolyte Effects on Micelle Formation -- 6.5.6.2 The Effect of pH -- 6.5.6.3 The Effects of Added Organic Materials -- 6.5.7 The Effect of Temperature on Micellization -- 6.6 Micelle Formation in Mixed Surfactant Systems -- 6.7 Micelle Formation in Nonaqueous Media -- 6.7.1 Aggregation in Polar Organic Solvents -- 6.7.2 Micelles in Nonpolar Solvents -- Chapter 7 Beyond Micelles: Higher Level Self-Assembled Aggregate Structures -- 7.1 The Importance of Surfactant Phase Information -- 7.2 Amphiphilic Fluids -- 7.2.1 Liquid Crystalline, Bicontinuous, and Microemulsion Structures -- 7.2.2 "Classical" Liquid Crystals -- 7.2.3 Liquid Crystalline Phases in Simple Binary Systems -- 7.3 Temperature and Additive Effects on Phase Behavior -- 7.4 Some Current Theoretical Analyses of Novel Mesophases -- 7.5 Vesicles and Bilayer Membranes -- 7.5.1 Vesicles -- 7.5.2 Polymerized Vesicles -- 7.6 Biological Membranes -- 7.6.1 Some Biological Implications of Mesophases -- 7.6.2 Membrane Surfactants and Lipids -- 7.7 Microemulsions.
7.7.1 Surfactants, Co-surfactants, and Microemulsion Formation -- 7.7.1.1 Ionic Surfactant Systems -- 7.7.1.2 Nonionic Surfactant Systems -- 7.7.2 Applications -- Chapter 8 Surfactant Self-Assembled Aggregates at Work -- 8.1 Solubilization in Surfactants Micelles -- 8.1.1 The "Geography" of Solubilization in Micelles -- 8.1.2 Surfactant Structure and the Solubilization Process -- 8.1.3 Solubilization and the Nature of the Additive -- 8.1.4 The Effect of Temperature on Solubilization Phenomena -- 8.1.5 The Effects of Nonelectrolyte Solutes -- 8.1.6 The Effects of Added Electrolyte -- 8.1.7 Miscellaneous Factors Affecting Micellar Solubilization -- 8.1.8 Hydrotropes -- 8.2 Micellar Catalysis -- 8.2.1 Micellar Catalysis in Aqueous Solution -- 8.2.2 Micellar Catalysis in Nonaqueous Solvents -- Chapter 9 Polymeric Surfactants and Surfactant-Polymer Interactions -- 9.1 Polymeric Surfactants and Amphiphiles -- 9.2 Some Basic Chemistry of Polymeric Surfactant Synthesis -- 9.2.1 The Modification of Natural Cellulosic Materials, Gums, and Proteins -- 9.2.2 Synthetic Polymeric Surfactants -- 9.3 Polymeric Surfactants at Interfaces: Structure and Methodology -- 9.4 The Interactions of "Normal" Surfactants with Polymers -- 9.4.1 Surfactant-Polymer Complex Formation -- 9.4.2 Nonionic Polymers -- 9.4.3 Ionic Polymers and Proteins -- 9.5 Polymers, Surfactants, and Solubilization -- 9.6 Surfactant-Polymer Interactions in Emulsion Polymerization -- Chapter 10 Emulsions -- 10.1 The Liquid-Liquid Interface -- 10.2 General Considerations of Emulsion Stability -- 10.2.1 The Lifetimes of Typical Emulsions -- 10.2.2 Theories of Emulsion Stability -- 10.3 Emulsion Type and the Nature of the Surfactant -- 10.4 Surface Activity and Emulsion Stability -- 10.5 Mixed Surfactant Systems and Interfacial Complexes -- 10.6 Amphiphile Mesophases and Emulsion Stability.
10.7 Surfactant Structure and Emulsion Stability -- 10.7.1 The Hydrophile-Lipophile Balance (HLB) -- 10.7.2 Phase Inversion Temperature (PIT) -- 10.7.3 Application of HLB and PIT in Emulsion Formulation -- 10.7.4 The Effects of Additives on the "Effective" HLB of Surfactants -- 10.8 Multiple Emulsions -- 10.8.1 Nomenclature for Multiple Emulsions -- 10.8.2 Preparation and Stability of Multiple Emulsions -- 10.8.3 Pathways for Primary Emulsion Breakdown -- 10.8.4 The Surfactants and Phase Components -- Chapter 11 Foams and Liquid Aerosols -- 11.1 The Physical Basis for Foam Formation -- 11.2 The Role of Surfactant in Foams -- 11.2.1 Foam Formation and Surfactant Structure -- 11.2.2 Amphiphilic Mesophases and Foam Stability -- 11.2.3 The Effects of Additives on Surfactant Foaming Properties -- 11.3 Foam Inhibition -- 11.4 Chemical Structures of Antifoaming Agents -- 11.5 A Summary of the Foaming and Antifoaming Activity of Additives -- 11.6 The Spreading Coefficient -- 11.7 Liquid Aerosols -- 11.7.1 The Formation of Liquid Aerosols -- 11.7.1.1 Spraying and Related Mechanisms of Mist and Fog Formation -- 11.7.1.2 Nozzle Atomization -- 11.7.1.3 Rotary Atomization -- 11.7.2 Aerosol Formation by Condensation -- 11.7.3 Colloidal Properties of Aerosols -- 11.7.3.1 The Dynamics of Aerosol Movement -- 11.7.3.2 Colloidal Interactions in Aerosols -- Chapter 12 Solid Surfaces: Adsorption, Wetting, and Dispersions -- 12.1 The Nature of Solid Surfaces -- 12.2 Liquid Versus Solid Surfaces -- 12.3 Adsorption at the Solid-Liquid Interface -- 12.3.1 Adsorption Isotherms -- 12.3.2 Mechanisms of Surfactant Adsorption -- 12.3.2.1 Dispersion Forces -- 12.3.2.2 Polarization and Dipolar Interactions -- 12.3.2.3 Electrostatic Interactions -- 12.3.3 The Electrical Double Layer -- 12.4 The Mechanics of Surfactant Adsorption.
12.4.1 Adsorption and the Nature of the Adsorbent Surface.
Tags from this library: No tags from this library for this title. Log in to add tags.
Star ratings
    Average rating: 0.0 (0 votes)
No physical items for this record

Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Chapter 1 An Overview of Surfactant Science and Technology -- 1.1 A Brief History of Surfactant Science and Technology -- 1.2 Surfactants in the Modern World -- 1.3 The Economics of Surfactant Science and Technology -- 1.4 The Near-Term Economic and Technological Future for Surfactants -- 1.5 Surfactants in the Environment -- 1.6 A Surfactant Glossary -- Chapter 2 The Classification of Surfactants -- 2.1 The Basic Structure of Amphiphilic Molecules -- 2.2 A Systematic Classification of Surfactants -- 2.2.1 Surfactant Solubilizing Groups -- 2.2.2 Making a Choice -- 2.3 The Generic Anatomy of Surfactants -- 2.3.1 The Many Faces of Dodecane -- 2.3.2 Surfactant Solubilizing Groups -- 2.3.3 Common Surfactant Hydrophobic Groups -- 2.3.3.1 The Natural Fatty Acids -- 2.3.3.2 Saturated Hydrocarbons or Paraffins -- 2.3.3.3 Olefins -- 2.3.3.4 Alkyl Benzenes -- 2.3.3.5 Alcohols -- 2.3.3.6 Alkyl Phenols -- 2.3.3.7 Polyoxypropylenes -- 2.3.3.8 Fluorocarbons -- 2.3.3.9 Silicone Surfactants -- 2.3.3.10 Miscellaneous Biological Structures -- 2.4 The Systematic Classification of Surfactants -- 2.5 Anionic Surfactants -- 2.5.1 Sulfate Esters -- 2.5.1.1 Fatty Alcohol Sulfates -- 2.5.1.2 Sulfated Fatty Acid Condensation Products -- 2.5.1.3 Sulfated Ethers -- 2.5.1.4 Sulfated Fats and Oils -- 2.5.2 Sulfonic Acid Salts -- 2.5.2.1 Aliphatic Sulfonates -- 2.5.2.2 Alkyl Aryl Sulfonates -- 2.5.2.3 α-Sulfocarboxylic Acids and Their Derivatives -- 2.5.2.4 Miscellaneous Sulfo-Ester and Amide Surfactants -- 2.5.2.5 Alkyl Glyceryl Ether Sulfonates -- 2.5.2.6 Lignin Sulfonates -- 2.5.3 Carboxylate Soaps and Detergents -- 2.5.4 Phosphoric Acid Esters and Related Surfactants -- 2.6 Cationic Surfactants -- 2.7 Nonionic Surfactants -- 2.7.1 Polyoxyethylene-Based Surfactants.

2.7.2 Derivatives of Polyglycerols and Other Polyols -- 2.7.3 Block Copolymer Nonionic Surfactants -- 2.7.4 Miscellaneous Nonionic Surfactants -- 2.8 Amphoteric Surfactants -- 2.8.1 Imidazoline Derivatives -- 2.8.2 Surface-Active Betaines and Sulfobetaines -- 2.8.3 Phosphatides and Related Amphoteric Surfactants -- Chapter 3 Surfactant Chemical Structures: Putting the Pieces Together -- 3.1 Surfactant Building Blocks -- 3.2 A Surfactant Family Tree -- 3.2.1 The Many Faces of Dodecane -- 3.3 Common Surfactant Hydrophobic Groups -- 3.3.1 The Natural Fatty Acids -- 3.3.2 Paraffins or Saturated Hydrocarbons -- 3.3.3 Olefins -- 3.3.4 Alkylbenzenes -- 3.3.5 Alcohols -- 3.3.6 Alkylphenols -- 3.3.7 Polyoxypropylene -- 3.3.8 Fluorocarbons -- 3.3.9 Silicone-Based Surfactants -- 3.3.10 Nonchemically Produced, a.k.a. "Natural" Surfactants -- Chapter 4 Natural Surfactants and Biosurfactants -- 4.1 What Makes a Surfactant "Natural"? -- 4.2 Surfactants Based on a Natural Sugar-Based Polar Head Groups -- 4.3 Biosurfactants -- 4.3.1 Biosurfactants as Nature Makes Them -- 4.3.2 Properties of Biosurfactants -- 4.3.3 Biosurfactant Classification -- 4.3.4 Some Aspects of Biosurfactant Production -- 4.3.5 Some Factors Affecting Biosurfactant Production -- 4.4 Biosurfactant Applications -- 4.5 Potential Limitations on the Commercial Use of Biosurfactants -- 4.6 Some Opportunities for Future Research and Development -- 4.7 Some Observations About the Future of Biosurfactants -- Chapter 5 Fluid Surfaces and Interfaces -- 5.1 Molecules at Interfaces -- 5.2 Interfaces and Adsorption Phenomena -- 5.2.1 A Thermodynamic Picture of Adsorption -- 5.2.2 Surface and Interfacial Tensions -- 5.2.3 The Effect of Surface Curvature -- 5.2.4 The Surface Tension of Solutions -- 5.2.5 Surfactants and the Reduction of Surface Tension.

5.2.6 Efficiency, Effectiveness, and Surfactant Structure -- Chapter 6 Surfactants in Solution: Self-Assembly and Micelle Formation -- 6.1 Surfactant Solubility -- 6.2 The Phase Spectrum of Surfactants in Solution -- 6.3 The History and Development of Micellar Theory -- 6.3.1 Manifestations of Micelle Formations -- 6.3.2 Thermodynamics of Dilute Surfactant Solutions -- 6.3.3 Classical Theories of Micelle Formation -- 6.3.4 Free Energy of Micellization -- 6.4 Molecular Geometry and the Formation of Association Colloids -- 6.5 Experimental Observations of Micellar Systems -- 6.5.1 Micellar Aggregation Numbers -- 6.5.2 The Critical Micelle Concentration -- 6.5.3 The Hydrophobic Group -- 6.5.4 The Hydrophilic Group -- 6.5.5 Counterion Effects on Micellization -- 6.5.6 The Effects of Additives on the Micellization Process -- 6.5.6.1 Electrolyte Effects on Micelle Formation -- 6.5.6.2 The Effect of pH -- 6.5.6.3 The Effects of Added Organic Materials -- 6.5.7 The Effect of Temperature on Micellization -- 6.6 Micelle Formation in Mixed Surfactant Systems -- 6.7 Micelle Formation in Nonaqueous Media -- 6.7.1 Aggregation in Polar Organic Solvents -- 6.7.2 Micelles in Nonpolar Solvents -- Chapter 7 Beyond Micelles: Higher Level Self-Assembled Aggregate Structures -- 7.1 The Importance of Surfactant Phase Information -- 7.2 Amphiphilic Fluids -- 7.2.1 Liquid Crystalline, Bicontinuous, and Microemulsion Structures -- 7.2.2 "Classical" Liquid Crystals -- 7.2.3 Liquid Crystalline Phases in Simple Binary Systems -- 7.3 Temperature and Additive Effects on Phase Behavior -- 7.4 Some Current Theoretical Analyses of Novel Mesophases -- 7.5 Vesicles and Bilayer Membranes -- 7.5.1 Vesicles -- 7.5.2 Polymerized Vesicles -- 7.6 Biological Membranes -- 7.6.1 Some Biological Implications of Mesophases -- 7.6.2 Membrane Surfactants and Lipids -- 7.7 Microemulsions.

7.7.1 Surfactants, Co-surfactants, and Microemulsion Formation -- 7.7.1.1 Ionic Surfactant Systems -- 7.7.1.2 Nonionic Surfactant Systems -- 7.7.2 Applications -- Chapter 8 Surfactant Self-Assembled Aggregates at Work -- 8.1 Solubilization in Surfactants Micelles -- 8.1.1 The "Geography" of Solubilization in Micelles -- 8.1.2 Surfactant Structure and the Solubilization Process -- 8.1.3 Solubilization and the Nature of the Additive -- 8.1.4 The Effect of Temperature on Solubilization Phenomena -- 8.1.5 The Effects of Nonelectrolyte Solutes -- 8.1.6 The Effects of Added Electrolyte -- 8.1.7 Miscellaneous Factors Affecting Micellar Solubilization -- 8.1.8 Hydrotropes -- 8.2 Micellar Catalysis -- 8.2.1 Micellar Catalysis in Aqueous Solution -- 8.2.2 Micellar Catalysis in Nonaqueous Solvents -- Chapter 9 Polymeric Surfactants and Surfactant-Polymer Interactions -- 9.1 Polymeric Surfactants and Amphiphiles -- 9.2 Some Basic Chemistry of Polymeric Surfactant Synthesis -- 9.2.1 The Modification of Natural Cellulosic Materials, Gums, and Proteins -- 9.2.2 Synthetic Polymeric Surfactants -- 9.3 Polymeric Surfactants at Interfaces: Structure and Methodology -- 9.4 The Interactions of "Normal" Surfactants with Polymers -- 9.4.1 Surfactant-Polymer Complex Formation -- 9.4.2 Nonionic Polymers -- 9.4.3 Ionic Polymers and Proteins -- 9.5 Polymers, Surfactants, and Solubilization -- 9.6 Surfactant-Polymer Interactions in Emulsion Polymerization -- Chapter 10 Emulsions -- 10.1 The Liquid-Liquid Interface -- 10.2 General Considerations of Emulsion Stability -- 10.2.1 The Lifetimes of Typical Emulsions -- 10.2.2 Theories of Emulsion Stability -- 10.3 Emulsion Type and the Nature of the Surfactant -- 10.4 Surface Activity and Emulsion Stability -- 10.5 Mixed Surfactant Systems and Interfacial Complexes -- 10.6 Amphiphile Mesophases and Emulsion Stability.

10.7 Surfactant Structure and Emulsion Stability -- 10.7.1 The Hydrophile-Lipophile Balance (HLB) -- 10.7.2 Phase Inversion Temperature (PIT) -- 10.7.3 Application of HLB and PIT in Emulsion Formulation -- 10.7.4 The Effects of Additives on the "Effective" HLB of Surfactants -- 10.8 Multiple Emulsions -- 10.8.1 Nomenclature for Multiple Emulsions -- 10.8.2 Preparation and Stability of Multiple Emulsions -- 10.8.3 Pathways for Primary Emulsion Breakdown -- 10.8.4 The Surfactants and Phase Components -- Chapter 11 Foams and Liquid Aerosols -- 11.1 The Physical Basis for Foam Formation -- 11.2 The Role of Surfactant in Foams -- 11.2.1 Foam Formation and Surfactant Structure -- 11.2.2 Amphiphilic Mesophases and Foam Stability -- 11.2.3 The Effects of Additives on Surfactant Foaming Properties -- 11.3 Foam Inhibition -- 11.4 Chemical Structures of Antifoaming Agents -- 11.5 A Summary of the Foaming and Antifoaming Activity of Additives -- 11.6 The Spreading Coefficient -- 11.7 Liquid Aerosols -- 11.7.1 The Formation of Liquid Aerosols -- 11.7.1.1 Spraying and Related Mechanisms of Mist and Fog Formation -- 11.7.1.2 Nozzle Atomization -- 11.7.1.3 Rotary Atomization -- 11.7.2 Aerosol Formation by Condensation -- 11.7.3 Colloidal Properties of Aerosols -- 11.7.3.1 The Dynamics of Aerosol Movement -- 11.7.3.2 Colloidal Interactions in Aerosols -- Chapter 12 Solid Surfaces: Adsorption, Wetting, and Dispersions -- 12.1 The Nature of Solid Surfaces -- 12.2 Liquid Versus Solid Surfaces -- 12.3 Adsorption at the Solid-Liquid Interface -- 12.3.1 Adsorption Isotherms -- 12.3.2 Mechanisms of Surfactant Adsorption -- 12.3.2.1 Dispersion Forces -- 12.3.2.2 Polarization and Dipolar Interactions -- 12.3.2.3 Electrostatic Interactions -- 12.3.3 The Electrical Double Layer -- 12.4 The Mechanics of Surfactant Adsorption.

12.4.1 Adsorption and the Nature of the Adsorbent Surface.

Description based on publisher supplied metadata and other sources.

Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2024. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.

There are no comments on this title.

to post a comment.

© 2024 Resource Centre. All rights reserved.