Palladium : Compounds, Production and Applications.
Brady, Kenneth M.
Palladium : Compounds, Production and Applications. - 1st ed. - 1 online resource (370 pages) - Materials Science and Technologies . - Materials Science and Technologies .
Intro -- PALLADIUM: COMPOUNDS, PRODUCTION AND APPLICATIONS -- PALLADIUM: COMPOUNDS, PRODUCTION AND APPLICATIONS -- CONTENTS -- PREFACE -- Chapter 1 SHAPE-CONTROLLED SYNTHESIS OF PALLADIUM NANOPARTICLES: MECHANISM OF FORMATION AND APPLICATIONS -- ABSTRACT -- I. INTRODUCTION -- II. COLLOIDAL SYNTHESIS TECHNIQUES -- III. NUCLEATION AND GROWTH OF NANOCRYSTALS -- III.1. The Artificial Division between Seeds and Nuclei -- III.2. Concept of Nucleation -- III.2.1. Homogeneous Nucleation -- III.2.2. Heterogeneous Nucleation -- III.3. Role of Twinned Defects -- III.4. Thermodynamic Versus Kinetic Growth Regime -- III.5. Oxidative Etching -- III.6. Surface Capping Agents: Thermodynamic Stabilization of Facets and Complexation Role -- III.7. Role of Foreign Ions -- III.8. Oriented Attachment Mechanism -- III.9. Conclusion -- IV. TYPES OF MORPHOLOGIES: SYNTHESIS STRATEGIES -- IV.1. Single Crystalline Pd Nanocrystals -- IV.1.1. Cubes - Nanobars -- IV.1.2. Cubooctahedra -- IV.1.3. Tetrahedra -- IV.1.4. Octahedra -- IV.1.5. Single Crystalline Nanorods -- IV.1.6. Nanoboxes - Nanocages -- IV.2. Single Twinned Nanoparticles -- IV.2.1. Triangular and Hexagonal Nanoplates -- IV.2.2. Bipyramidal Nanoparticles -- IV.2.3. Single Twinned Nanorods or Nanodisks -- IV.3. Multiply-Twinned Nanoparticles -- IV.3.1. Decahedra -- IV.3.2. Fivefold Twinned Nanorods -- IV.3.3. Multiply-Twinned Icosahedra -- IV.4. Complex Pd Morphologies -- IV.4.1. Kinetic Control and the Formation of Multipods and Nanodendritic Structures -- IV.4.2. Other Complex Morphologies -- V. APPLICATIONS -- V.1. Applications Based on the SERS Effect -- V.2. Catalytic and Electrocatalytic Applications -- V.2.1. Catalytic Applications -- V.2.2. Electrocatalytic Applications -- CONCLUSION -- REFERENCES -- Chapter 2 PALLADIUM IN GAS-PHASE PROCESSES OF ENVIRONMENTAL CATALYSIS -- ABSTRACT -- INTRODUCTION. CARBON MONOXIDE OXIDATION ON MODEL PALLADIUM-CONTAINING CATALYSTS -- FEATURES OF THE RED-OX INTERACTIONS (СO, Н2, СNHM, О2, NOX) ON PALLADIUM CATALYSTS -- PALLADIUM IN COMPOSITION OF NANOPHASE STRUCTURED CATALYSTS FOR HIGH-TEMPERATURE NITROGEN OXIDES REDUCTION BY METHANE -- STRUCTURAL-FUNCTIONAL DESIGN OF THE PALLADIUM-CONTAINING CATALYSTS FOR CONTROL OF INTERNAL COMBUSTION ENGINES EMISSIONS -- PALLADIUM AS CO-CATALYST IN THE COMPOSITION OF STRUCTURED OXIDE COMPOSITES -- SULFUR RESISTANCE OF PALLADIUM-CONTAINING CATALYSTS IN THE PROCESSES OF CARBON MONOXIDE AND METHANE OXIDATION -- Effect of Sulfur Dioxide on Carbon Monoxide Oxidation over Pd-Containing Catalysts -- Tolerance to Sulfur Compounds of Anodic Materials of SOFCs with Direct Oxidation of Hydrocarbon Fuels -- CONCLUSION -- REFERENCES -- Chapter 3 PALLADIUM COMPLEXES OF N-HETEROCYCLIC CARBENES IN HOMOGENEOUS CATALYSIS AND BIOMEDICAL APPLICATIONS -- ABSTRACT -- INTRODUCTION -- Palladium(0) N-Heterocyclic Carbene Complexes -- Palladium(II) N-Heterocyclic Carbene Complexes -- Palladium(IV) N-Heterocyclic Carbene Complexes -- C−C Bond Forming Reactions -- Suzuki-Miyaura Cross-Coupling Reaction -- Heck−Mizoroki Reaction -- Stille Cross-Coupling Reaction -- Kumada-Tamao-Corriu (KTC) Cross-Coupling Reaction -- Negishi Cross-Coupling Reaction -- Hiyama Cross-Coupling Reaction -- Sonogashira Cross-Coupling Reactions -- Arylation Reaction -- (I). Arylation of Enolates -- (II). Direct Arylation Reactions -- Hydroarylation Reactions -- C−N Bond Formation Reaction -- Buchwald−Hartwig Amination Reaction -- Hydroamination Reaction -- Oxidation Reaction -- (i). Oxidation of Alcohols -- (II). Wacker Oxidation and Oxidative Cyclization Reactions -- Reduction Reaction -- Tsuji-Trost Alkylation Reaction -- Telomerization Reactions -- (I). Telomerization of Dienes with Alcohols. (ii). Telomerization of Dienes with Amines -- Polymerization Reactions -- Cycloisomerization Reactions -- Addition Reactions -- Domino Reactions -- Palladium in Biomedical Application -- CONCLUSIONS -- REFERENCES -- Chapter 4 SUPPORTED PD NANOPARTICLES: METHODS AND APPLICATIONS -- ABSTRACT -- 1. INTRODUCTION -- 2. NATURE OF SUPPORTS: POROUS/NON POROUS MATERIALS -- 2.1. Porous Materials -- 2.1.1. Carbonaceous Materials -- 2.1.2. (Bio)Polymers -- 2.1.3. Metal Oxides -- 2.2. Non Porous Materials -- 3. SUPPORTED PD NANOPARTICLES PREPARATION ROUTES -- 3.1. Physical Routes -- 3.1.1. Sonochemistry -- 3.1.2. Microwave Irradiation (MWI) -- 3.1.3. Pulsed Laser Ablation (PLA) -- 3.1.4. Supercritical Fluids (SCF) -- 3.1.5. Plasma -- 3.1.6. Other Physical Routes -- 3.2. Chemical Routes -- 3.2.1. Traditional Methods -- 3.2.1.1. Impregnation -- 3.2.1.2.Grafting -- 3.2.1.3.Co-Precipitation -- 3.2.2. Novel Methods -- 3.2.2.1. Microemulsions -- 3.2.2.2. Photochemistry -- 3.2.2.3. Chemical Vapor Deposition (CVD) -- 3.2.2.4. 'In Situ' Incorporation of Palladium Nanoparticles -- 3.2.3. Other Chemical Methods -- 3.3. Physico-Chemical Routes -- 3.3.1. Sonoelectrochemistry -- 3.3.2. Flame Spray Pyrolysis -- 4. CATALYTIC APPLICATIONS OF SUPPORTED PD NANOPARTICLES -- 5. FUTURE PROSPECTS AND OUTLOOK -- 5.1. Sustainable Preparation of Pd SNP -- 5.2. Sustainable and Future Catalytic Applications -- CONCLUSIONS -- ACKNOWLEDGMENTS -- REFERENCES -- Chapter 5 APPLICATION OF PALLADIUM IN OHMIC CONTACTS TO GAAS -- ABSTRACT -- 1. INTRODUCTION -- 2. EXPERIMENTAL -- 3. SURFACE CLEANING OF GAAS SUBSTRATES -- 4. THICKNESS OPTIMIZATION OF PD AND GE LAYERS IN GE/PD/GAAS CONTACT STRUCTURE -- 5. VERIFICATION OF SOLID PHASE REGROWTH MECHANISM -- 6. ROLE OF REACTIVE METALS IN THE GEPD METALLIZATION -- 7. APPLICATION OF INDIUM IN PDGE METALLIZATION. 8. ROLE OF SELENIUM IN PDGE METALLIZATION -- 9. THERMAL STABILITY OF PDGE OHMIC CONTACTS -- 10. APPLICATION OF PDGE OHMIC CONTACTS IN UHF SCHOTTKY DIODES -- CONCLUSION -- ACKNOWLEDGMENT -- REFERENCES -- Chapter 6 PALLADIUM COMPLEXES WITH POTENTIAL PHARMACOLOGICAL ACTIVITIES -- ABSTRACT -- 1. INTRODUCTION -- 2. PALLADIUM(II) COMPLEXES BEARING NITROGEN OR PHOSPHINE DONOR LIGANDS -- 2.1. Antitumor Activity -- Other Biological Activities -- 3. PALLADIUM(II) COMPLEXES BEARING NITROGEN AND SULFUR/OXYGEN MIXED DONOR LIGANDS -- 3.1. Antitumor Activity -- 3.2. Other Biological Activities -- CONCLUSION -- ACKNOWLEDGMENT -- REFERENCES -- Chapter 7 PALLADIUM NANOSTRUCTURE FOR FUEL CELL SYSTEM -- ABSTRACT -- 1. INTRODUCTION -- 2. PD-CARBON NANOSTRUCTURE AND CHARACTERIZATION -- 3. APPLICATION AND MEASUREMENT OF PD-CARBON NANOSTRUCTURE IN FUEL CELL SYSTEM -- CONCLUSION -- REFERENCES -- Chapter 8 THE APPLICATION OF SUPPORTED PALLADIUM CATALYSTS IN CO- AND TERPOLYMERIZATION REACTIONS OF CARBON MONOXIDE AND OLEFINS -- ABSTRACT -- INTRODUCTION -- RESULTS AND DISCUSSION -- The Supported Catalyst Investigation -- Reactions of CO/C2H4 Copolymerization and CO/C2H4/C3H6 Terpolymerization in the Presence of Supported Catalysts -- The Characterization of the Terpolymer by Means of IR and 13C NMR Spectroscopy -- CONCLUSION -- REFERENCES -- Chapter 9 PORPHYRIN PALLADIUM (II) COMPLEXES STABLE INTERMEDIATES IN SOME REDOX AND CATALYTIC REACTIONS -- ABSTRACT -- INTRODUCTION -- EXPERIMENTAL -- Materials -- Spectroscopic and Kinetic Measurements -- RESULTS -- Kinetics of Oxidation Reactions of Palladium (II) Porphyrins by Aerated Sulfuric Acid -- Alkaline Decomposition of Hydrogen Peroxide in a Water-Dimethylformamide Medium Catalyzed by Palladium (II) Porphyrines -- CONCLUSION -- ACKNOWLEDGMENTS -- REFERENCES. Chapter 10 COMPOSITE PALLADIUM MEMBRANES WITH IMPROVED DURABILITY TOWARD HYDROGEN EMBRITTLEMENT* -- ABSTRACT -- 1. INTRODUCTION -- Pd and Ag Alloy Membranes -- Simultaneous Plating of Palladium and Silver -- Hydrogen Permeation of the Pd-Ag Alloy Membranes -- "Pore-Fill" Type Palladium Membranes -- Fabrication of "Pore-Fill" Type Membranes -- REFERENCES -- Chapter 11 SELECTIVITY ON THE COORDINATION SITE AND THE BONDING MODE OF PHOSPHORUS YLIDES TOWARDS PALLADIUM AND PLATINUM SUBSTRATES* -- ABSTRACT -- INTRODUCTION -- REACTIVITY OF P-YLIDES WITH (8-QUINOLYLMETHYL-C,N)PALLADIUM -- REACTIVITY OF P-YLIDES WITH (2-PHENYLPYRIDINATE-C,N) -- REACTIVITY OF P-YLIDES WITH PINCER COMPLEXES -- EXPERIMENTAL SECTION -- Safety Note -- General Methods -- Synthesis of the Starting Compounds -- Synthesis of [Pd(phpy)(NCMe)2]ClO4 (4) -- Synthesis of the Ylide Complexes -- ACKNOWLEDGMENTS -- REFERENCES -- INDEX -- Blank Page.
9781611220841
Palladium compounds -- Industrial applications.
Palladium -- Metallurgy.
Electronic books.
TA480.P35 -- P35 2011eb
620/.5
Palladium : Compounds, Production and Applications. - 1st ed. - 1 online resource (370 pages) - Materials Science and Technologies . - Materials Science and Technologies .
Intro -- PALLADIUM: COMPOUNDS, PRODUCTION AND APPLICATIONS -- PALLADIUM: COMPOUNDS, PRODUCTION AND APPLICATIONS -- CONTENTS -- PREFACE -- Chapter 1 SHAPE-CONTROLLED SYNTHESIS OF PALLADIUM NANOPARTICLES: MECHANISM OF FORMATION AND APPLICATIONS -- ABSTRACT -- I. INTRODUCTION -- II. COLLOIDAL SYNTHESIS TECHNIQUES -- III. NUCLEATION AND GROWTH OF NANOCRYSTALS -- III.1. The Artificial Division between Seeds and Nuclei -- III.2. Concept of Nucleation -- III.2.1. Homogeneous Nucleation -- III.2.2. Heterogeneous Nucleation -- III.3. Role of Twinned Defects -- III.4. Thermodynamic Versus Kinetic Growth Regime -- III.5. Oxidative Etching -- III.6. Surface Capping Agents: Thermodynamic Stabilization of Facets and Complexation Role -- III.7. Role of Foreign Ions -- III.8. Oriented Attachment Mechanism -- III.9. Conclusion -- IV. TYPES OF MORPHOLOGIES: SYNTHESIS STRATEGIES -- IV.1. Single Crystalline Pd Nanocrystals -- IV.1.1. Cubes - Nanobars -- IV.1.2. Cubooctahedra -- IV.1.3. Tetrahedra -- IV.1.4. Octahedra -- IV.1.5. Single Crystalline Nanorods -- IV.1.6. Nanoboxes - Nanocages -- IV.2. Single Twinned Nanoparticles -- IV.2.1. Triangular and Hexagonal Nanoplates -- IV.2.2. Bipyramidal Nanoparticles -- IV.2.3. Single Twinned Nanorods or Nanodisks -- IV.3. Multiply-Twinned Nanoparticles -- IV.3.1. Decahedra -- IV.3.2. Fivefold Twinned Nanorods -- IV.3.3. Multiply-Twinned Icosahedra -- IV.4. Complex Pd Morphologies -- IV.4.1. Kinetic Control and the Formation of Multipods and Nanodendritic Structures -- IV.4.2. Other Complex Morphologies -- V. APPLICATIONS -- V.1. Applications Based on the SERS Effect -- V.2. Catalytic and Electrocatalytic Applications -- V.2.1. Catalytic Applications -- V.2.2. Electrocatalytic Applications -- CONCLUSION -- REFERENCES -- Chapter 2 PALLADIUM IN GAS-PHASE PROCESSES OF ENVIRONMENTAL CATALYSIS -- ABSTRACT -- INTRODUCTION. CARBON MONOXIDE OXIDATION ON MODEL PALLADIUM-CONTAINING CATALYSTS -- FEATURES OF THE RED-OX INTERACTIONS (СO, Н2, СNHM, О2, NOX) ON PALLADIUM CATALYSTS -- PALLADIUM IN COMPOSITION OF NANOPHASE STRUCTURED CATALYSTS FOR HIGH-TEMPERATURE NITROGEN OXIDES REDUCTION BY METHANE -- STRUCTURAL-FUNCTIONAL DESIGN OF THE PALLADIUM-CONTAINING CATALYSTS FOR CONTROL OF INTERNAL COMBUSTION ENGINES EMISSIONS -- PALLADIUM AS CO-CATALYST IN THE COMPOSITION OF STRUCTURED OXIDE COMPOSITES -- SULFUR RESISTANCE OF PALLADIUM-CONTAINING CATALYSTS IN THE PROCESSES OF CARBON MONOXIDE AND METHANE OXIDATION -- Effect of Sulfur Dioxide on Carbon Monoxide Oxidation over Pd-Containing Catalysts -- Tolerance to Sulfur Compounds of Anodic Materials of SOFCs with Direct Oxidation of Hydrocarbon Fuels -- CONCLUSION -- REFERENCES -- Chapter 3 PALLADIUM COMPLEXES OF N-HETEROCYCLIC CARBENES IN HOMOGENEOUS CATALYSIS AND BIOMEDICAL APPLICATIONS -- ABSTRACT -- INTRODUCTION -- Palladium(0) N-Heterocyclic Carbene Complexes -- Palladium(II) N-Heterocyclic Carbene Complexes -- Palladium(IV) N-Heterocyclic Carbene Complexes -- C−C Bond Forming Reactions -- Suzuki-Miyaura Cross-Coupling Reaction -- Heck−Mizoroki Reaction -- Stille Cross-Coupling Reaction -- Kumada-Tamao-Corriu (KTC) Cross-Coupling Reaction -- Negishi Cross-Coupling Reaction -- Hiyama Cross-Coupling Reaction -- Sonogashira Cross-Coupling Reactions -- Arylation Reaction -- (I). Arylation of Enolates -- (II). Direct Arylation Reactions -- Hydroarylation Reactions -- C−N Bond Formation Reaction -- Buchwald−Hartwig Amination Reaction -- Hydroamination Reaction -- Oxidation Reaction -- (i). Oxidation of Alcohols -- (II). Wacker Oxidation and Oxidative Cyclization Reactions -- Reduction Reaction -- Tsuji-Trost Alkylation Reaction -- Telomerization Reactions -- (I). Telomerization of Dienes with Alcohols. (ii). Telomerization of Dienes with Amines -- Polymerization Reactions -- Cycloisomerization Reactions -- Addition Reactions -- Domino Reactions -- Palladium in Biomedical Application -- CONCLUSIONS -- REFERENCES -- Chapter 4 SUPPORTED PD NANOPARTICLES: METHODS AND APPLICATIONS -- ABSTRACT -- 1. INTRODUCTION -- 2. NATURE OF SUPPORTS: POROUS/NON POROUS MATERIALS -- 2.1. Porous Materials -- 2.1.1. Carbonaceous Materials -- 2.1.2. (Bio)Polymers -- 2.1.3. Metal Oxides -- 2.2. Non Porous Materials -- 3. SUPPORTED PD NANOPARTICLES PREPARATION ROUTES -- 3.1. Physical Routes -- 3.1.1. Sonochemistry -- 3.1.2. Microwave Irradiation (MWI) -- 3.1.3. Pulsed Laser Ablation (PLA) -- 3.1.4. Supercritical Fluids (SCF) -- 3.1.5. Plasma -- 3.1.6. Other Physical Routes -- 3.2. Chemical Routes -- 3.2.1. Traditional Methods -- 3.2.1.1. Impregnation -- 3.2.1.2.Grafting -- 3.2.1.3.Co-Precipitation -- 3.2.2. Novel Methods -- 3.2.2.1. Microemulsions -- 3.2.2.2. Photochemistry -- 3.2.2.3. Chemical Vapor Deposition (CVD) -- 3.2.2.4. 'In Situ' Incorporation of Palladium Nanoparticles -- 3.2.3. Other Chemical Methods -- 3.3. Physico-Chemical Routes -- 3.3.1. Sonoelectrochemistry -- 3.3.2. Flame Spray Pyrolysis -- 4. CATALYTIC APPLICATIONS OF SUPPORTED PD NANOPARTICLES -- 5. FUTURE PROSPECTS AND OUTLOOK -- 5.1. Sustainable Preparation of Pd SNP -- 5.2. Sustainable and Future Catalytic Applications -- CONCLUSIONS -- ACKNOWLEDGMENTS -- REFERENCES -- Chapter 5 APPLICATION OF PALLADIUM IN OHMIC CONTACTS TO GAAS -- ABSTRACT -- 1. INTRODUCTION -- 2. EXPERIMENTAL -- 3. SURFACE CLEANING OF GAAS SUBSTRATES -- 4. THICKNESS OPTIMIZATION OF PD AND GE LAYERS IN GE/PD/GAAS CONTACT STRUCTURE -- 5. VERIFICATION OF SOLID PHASE REGROWTH MECHANISM -- 6. ROLE OF REACTIVE METALS IN THE GEPD METALLIZATION -- 7. APPLICATION OF INDIUM IN PDGE METALLIZATION. 8. ROLE OF SELENIUM IN PDGE METALLIZATION -- 9. THERMAL STABILITY OF PDGE OHMIC CONTACTS -- 10. APPLICATION OF PDGE OHMIC CONTACTS IN UHF SCHOTTKY DIODES -- CONCLUSION -- ACKNOWLEDGMENT -- REFERENCES -- Chapter 6 PALLADIUM COMPLEXES WITH POTENTIAL PHARMACOLOGICAL ACTIVITIES -- ABSTRACT -- 1. INTRODUCTION -- 2. PALLADIUM(II) COMPLEXES BEARING NITROGEN OR PHOSPHINE DONOR LIGANDS -- 2.1. Antitumor Activity -- Other Biological Activities -- 3. PALLADIUM(II) COMPLEXES BEARING NITROGEN AND SULFUR/OXYGEN MIXED DONOR LIGANDS -- 3.1. Antitumor Activity -- 3.2. Other Biological Activities -- CONCLUSION -- ACKNOWLEDGMENT -- REFERENCES -- Chapter 7 PALLADIUM NANOSTRUCTURE FOR FUEL CELL SYSTEM -- ABSTRACT -- 1. INTRODUCTION -- 2. PD-CARBON NANOSTRUCTURE AND CHARACTERIZATION -- 3. APPLICATION AND MEASUREMENT OF PD-CARBON NANOSTRUCTURE IN FUEL CELL SYSTEM -- CONCLUSION -- REFERENCES -- Chapter 8 THE APPLICATION OF SUPPORTED PALLADIUM CATALYSTS IN CO- AND TERPOLYMERIZATION REACTIONS OF CARBON MONOXIDE AND OLEFINS -- ABSTRACT -- INTRODUCTION -- RESULTS AND DISCUSSION -- The Supported Catalyst Investigation -- Reactions of CO/C2H4 Copolymerization and CO/C2H4/C3H6 Terpolymerization in the Presence of Supported Catalysts -- The Characterization of the Terpolymer by Means of IR and 13C NMR Spectroscopy -- CONCLUSION -- REFERENCES -- Chapter 9 PORPHYRIN PALLADIUM (II) COMPLEXES STABLE INTERMEDIATES IN SOME REDOX AND CATALYTIC REACTIONS -- ABSTRACT -- INTRODUCTION -- EXPERIMENTAL -- Materials -- Spectroscopic and Kinetic Measurements -- RESULTS -- Kinetics of Oxidation Reactions of Palladium (II) Porphyrins by Aerated Sulfuric Acid -- Alkaline Decomposition of Hydrogen Peroxide in a Water-Dimethylformamide Medium Catalyzed by Palladium (II) Porphyrines -- CONCLUSION -- ACKNOWLEDGMENTS -- REFERENCES. Chapter 10 COMPOSITE PALLADIUM MEMBRANES WITH IMPROVED DURABILITY TOWARD HYDROGEN EMBRITTLEMENT* -- ABSTRACT -- 1. INTRODUCTION -- Pd and Ag Alloy Membranes -- Simultaneous Plating of Palladium and Silver -- Hydrogen Permeation of the Pd-Ag Alloy Membranes -- "Pore-Fill" Type Palladium Membranes -- Fabrication of "Pore-Fill" Type Membranes -- REFERENCES -- Chapter 11 SELECTIVITY ON THE COORDINATION SITE AND THE BONDING MODE OF PHOSPHORUS YLIDES TOWARDS PALLADIUM AND PLATINUM SUBSTRATES* -- ABSTRACT -- INTRODUCTION -- REACTIVITY OF P-YLIDES WITH (8-QUINOLYLMETHYL-C,N)PALLADIUM -- REACTIVITY OF P-YLIDES WITH (2-PHENYLPYRIDINATE-C,N) -- REACTIVITY OF P-YLIDES WITH PINCER COMPLEXES -- EXPERIMENTAL SECTION -- Safety Note -- General Methods -- Synthesis of the Starting Compounds -- Synthesis of [Pd(phpy)(NCMe)2]ClO4 (4) -- Synthesis of the Ylide Complexes -- ACKNOWLEDGMENTS -- REFERENCES -- INDEX -- Blank Page.
9781611220841
Palladium compounds -- Industrial applications.
Palladium -- Metallurgy.
Electronic books.
TA480.P35 -- P35 2011eb
620/.5