Modern Heterogeneous Catalysis : An Introduction.
van Santen, Rutger A.
Modern Heterogeneous Catalysis : An Introduction. - 1st ed. - 1 online resource (731 pages) - New York Academy of Sciences Series . - New York Academy of Sciences Series .
Intro -- Title Page -- Copyright -- Dedication -- Table of Contents -- Preface -- Acknowledgments -- Arrangement of This Book -- Part I: Physical Chemistry and Kinetics -- Chapter 1: Heterogeneous Catalysis -- 1.1 What is Heterogeneous Catalysis? -- 1.2 Early Developments -- 1.3 The Three Basic Laws of Catalysis -- References -- Chapter 2: Heterogeneous Catalytic Processes -- 2.1 Introduction -- 2.2 Important Heterogeneous Catalytic Reactions and Processes -- 2.3 Summary -- References -- Chapter 3: Physical Chemistry, Elementary Kinetics -- 3.1 Introduction -- 3.2 Catalyst Characterization -- 3.3 Elementary Kinetics -- 3.4 Transient Kinetics: The Determination of Site Concentration -- 3.5 Diffusion -- References -- Chapter 4: The State of the Working Catalyst -- 4.1 Introduction -- 4.2 Surface Reconstruction -- 4.3 Compound Formation: Activation and Deactivation -- 4.4 Supported Small Metal Particles -- 4.5 Structure Sensitivity of Transition Metal Particle Catalysts -- 4.6 Alloys and Other Promotors -- 4.7 The Working Zeolite Catalysts -- 4.8 The State of the Mixed Oxide Surface -- 4.9 Summary -- References -- Chapter 5: Advanced Kinetics: Breakdown of Mean Field Approximation -- 5.1 Introduction -- 5.2 The Kinetic Monte Carlo Method: RuO2 Catalyzed Oxidation -- 5.3 Single Molecule Spectroscopy -- 5.4 Catalytic Self-Organizing Systems -- References -- Part II: Molecular Heterogeneous Catalysis -- Chapter 6: Basic Quantum-Chemical Concepts, The Chemical Bond Revisited (Jointly Written with I. Tranca) -- 6.1 Introduction -- 6.2 The Definitions of Partial Density of States and Bond Order Overlap Population -- 6.3 Diatomic Molecules that Have σ Bonds -- 6.4 Diatomic Molecules with π Bonds -- 6.5 Comparison of the Electronic Structure of Molecules and Solids -- 6.6 Chemical Bonding in Transition Metals -- Appendix -- References. Chapter 7: Chemical Bonding and Reactivity of Transition Metal Surfaces -- 7.1 Introduction -- 7.2 The Nature of the Surface Chemical Bond -- 7.3 The Transition States of Elementary Surface Reactions -- 7.4 Reactivity of Surfaces at High Coverage -- References -- Chapter 8: Mechanisms of Transition Metal Catalyzed Reactions -- 8.1 Introduction -- 8.2 Hydrogenation Reactions -- 8.3 Oxidation Reactions -- 8.4 Uniqueness of a Metal for a Particular Selective Reaction -- References -- Chapter 9: Solid Acid Catalysis, Theory and Reaction Mechanisms -- 9.1 Introduction -- 9.2 Elementary Theory of Surface Acidity and Basicity -- 9.3 Mechanism of Reactions Catalyzed by Zeolite Protons -- 9.4 Acid Catalysis and Hydride Transfer by Enzyme Catalysts -- References -- Chapter 10: Zeolitic Non-Redox and Redox Catalysis, Lewis Acid Catalysis -- 10.1 Introduction -- 10.2 Non-Reducible Cations -- The Electrostatic Field -- 10.3 Catalysis with Non-Framework Non-Reducible Cations -- 10.4 Catalysis by Non-Framework Redox Complexes -- 10.5 Related Homogeneous and Enzyme Oxidation Catalysts -- 10.6 Lewis Acid Catalysis by Non-Reducible Cations Located in the Zeolitic Framework -- 10.7 Catalysis by Redox Cations located in the Zeolitic Framework: The Thomas Oxidation Catalysts -- 10.8 Summary of Zeolite Catalysis -- References -- Chapter 11: Reducible Solid State Catalysts -- 11.1 Introduction -- 11.2 Chemical Bonding of Transition Metal Oxides and Their Surfaces -- 11.3 Mechanism of Oxidation Catalysis by Group V, VI Metal Oxides -- 11.4 Metathesis and Polymerization Catalysis: Surface Coordination Complexes -- 11.5 Sulfide Catalysts -- 11.6 Electrocatalysis: The Oxygen Evolution Reaction (OER) -- 11.7 Photocatalytic Water Splitting -- References -- Index -- End User License Agreement.
9783527694501
Heterogeneous catalysis.
Electronic books.
QD505 .S26 2017
Modern Heterogeneous Catalysis : An Introduction. - 1st ed. - 1 online resource (731 pages) - New York Academy of Sciences Series . - New York Academy of Sciences Series .
Intro -- Title Page -- Copyright -- Dedication -- Table of Contents -- Preface -- Acknowledgments -- Arrangement of This Book -- Part I: Physical Chemistry and Kinetics -- Chapter 1: Heterogeneous Catalysis -- 1.1 What is Heterogeneous Catalysis? -- 1.2 Early Developments -- 1.3 The Three Basic Laws of Catalysis -- References -- Chapter 2: Heterogeneous Catalytic Processes -- 2.1 Introduction -- 2.2 Important Heterogeneous Catalytic Reactions and Processes -- 2.3 Summary -- References -- Chapter 3: Physical Chemistry, Elementary Kinetics -- 3.1 Introduction -- 3.2 Catalyst Characterization -- 3.3 Elementary Kinetics -- 3.4 Transient Kinetics: The Determination of Site Concentration -- 3.5 Diffusion -- References -- Chapter 4: The State of the Working Catalyst -- 4.1 Introduction -- 4.2 Surface Reconstruction -- 4.3 Compound Formation: Activation and Deactivation -- 4.4 Supported Small Metal Particles -- 4.5 Structure Sensitivity of Transition Metal Particle Catalysts -- 4.6 Alloys and Other Promotors -- 4.7 The Working Zeolite Catalysts -- 4.8 The State of the Mixed Oxide Surface -- 4.9 Summary -- References -- Chapter 5: Advanced Kinetics: Breakdown of Mean Field Approximation -- 5.1 Introduction -- 5.2 The Kinetic Monte Carlo Method: RuO2 Catalyzed Oxidation -- 5.3 Single Molecule Spectroscopy -- 5.4 Catalytic Self-Organizing Systems -- References -- Part II: Molecular Heterogeneous Catalysis -- Chapter 6: Basic Quantum-Chemical Concepts, The Chemical Bond Revisited (Jointly Written with I. Tranca) -- 6.1 Introduction -- 6.2 The Definitions of Partial Density of States and Bond Order Overlap Population -- 6.3 Diatomic Molecules that Have σ Bonds -- 6.4 Diatomic Molecules with π Bonds -- 6.5 Comparison of the Electronic Structure of Molecules and Solids -- 6.6 Chemical Bonding in Transition Metals -- Appendix -- References. Chapter 7: Chemical Bonding and Reactivity of Transition Metal Surfaces -- 7.1 Introduction -- 7.2 The Nature of the Surface Chemical Bond -- 7.3 The Transition States of Elementary Surface Reactions -- 7.4 Reactivity of Surfaces at High Coverage -- References -- Chapter 8: Mechanisms of Transition Metal Catalyzed Reactions -- 8.1 Introduction -- 8.2 Hydrogenation Reactions -- 8.3 Oxidation Reactions -- 8.4 Uniqueness of a Metal for a Particular Selective Reaction -- References -- Chapter 9: Solid Acid Catalysis, Theory and Reaction Mechanisms -- 9.1 Introduction -- 9.2 Elementary Theory of Surface Acidity and Basicity -- 9.3 Mechanism of Reactions Catalyzed by Zeolite Protons -- 9.4 Acid Catalysis and Hydride Transfer by Enzyme Catalysts -- References -- Chapter 10: Zeolitic Non-Redox and Redox Catalysis, Lewis Acid Catalysis -- 10.1 Introduction -- 10.2 Non-Reducible Cations -- The Electrostatic Field -- 10.3 Catalysis with Non-Framework Non-Reducible Cations -- 10.4 Catalysis by Non-Framework Redox Complexes -- 10.5 Related Homogeneous and Enzyme Oxidation Catalysts -- 10.6 Lewis Acid Catalysis by Non-Reducible Cations Located in the Zeolitic Framework -- 10.7 Catalysis by Redox Cations located in the Zeolitic Framework: The Thomas Oxidation Catalysts -- 10.8 Summary of Zeolite Catalysis -- References -- Chapter 11: Reducible Solid State Catalysts -- 11.1 Introduction -- 11.2 Chemical Bonding of Transition Metal Oxides and Their Surfaces -- 11.3 Mechanism of Oxidation Catalysis by Group V, VI Metal Oxides -- 11.4 Metathesis and Polymerization Catalysis: Surface Coordination Complexes -- 11.5 Sulfide Catalysts -- 11.6 Electrocatalysis: The Oxygen Evolution Reaction (OER) -- 11.7 Photocatalytic Water Splitting -- References -- Index -- End User License Agreement.
9783527694501
Heterogeneous catalysis.
Electronic books.
QD505 .S26 2017