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Atom Movements.

By: Material type: TextTextSeries: Hors CollectionPublisher: Les Ulis : EDP Sciences, 2006Copyright date: ©2006Edition: 1st edDescription: 1 online resource (603 pages)Content type:
  • text
Media type:
  • computer
Carrier type:
  • online resource
ISBN:
  • 9782759801725
Subject(s): Genre/Form: Additional physical formats: Print version:: Atom MovementsLOC classification:
  • QD543 -- .P5813 1991eb
Online resources:
Contents:
Intro -- TABLE OF CONTENTS -- Preface -- Foreword -- Foreword to the English edition -- Translator's acknowledgments -- General Bibliography -- Notation -- CHAPTER I: DIFFUSION AND DRIFT -- I. Flux of particles. Fick's equation -- II. Time-dependent case -- III. Solutions of the diffusion equation (or Fick's second law) -- IV. Relation between drift and diffusion. The Nernst-Einstein equation -- V. The nature of the driving force -- VI. A variety of diffusion processes and generalization of Fick's law -- VII. Diffusion with phase change. Multiphase diffusion -- APPENDIX I: Methods for solving the diffusion equation -- APPENDIX II: Diffusion in three dimensions -- APPENDIX III: Conservation at a moving boundary -- CHAPTER II: ATOMIC THEORY OF DIFFUSION -- I. A simplified model -- II. General theory of random walk -- III. Expressions for the mean-square displacement (X²) and for the diffusion coefficient -- IV. Diffusion in the presence of a driving force -- V. Explicit form of the function W (X, pi) -- VI. Variable jump distance -- VII. Correlation functions -- VIII. Limitations of Fick's law -- APPENDIX: Some definitions -- CHAPTER III: DIFFUSION MECHANISMS AND CORRELATION EFFECTS -- I. Mechanisms of diffusion -- II. Definition of the correlation factor -- III. The encounter model -- IV. A simple simulation of self-diffusion and electromigration -- V. Methods of calculating the correlation factor -- VI. Types of correlation factors -- VII. Migration of point defects -- Effect of temperature -- APPENDIX I: Calculation of (cos theta) -- APPENDIX II: Percolation -- CHAPTER IV: SELF-DIFFUSION -- I. The self-diffusion coefficient -- II. Variation of the diffusion coefficient with temperature -- III. Anisotropy of diffusion -- IV. Deviations from the Arrhenius law -- V. The isotope effect -- VI. Effect of pressure -- VII. Empirical correlations.
VIII. Self-diffusion in metals -- IX. Self-diffusion in semiconductors -- X. Semi-diffusion in ionic crystals -- XI. Molecular crystals -- CHAPTER V: SOLUTE DIFFUSION IN PURE MATERIALS. DIFFUSION IN ALLOYS -- I. Introduction -- II. Solute diffusion at infinite dilution -- III. Interstitial solid solutions -- IV. Ionic crystals -- V. Semiconductors -- VI. Dilute alloys -- VII. Diffusion in homogeneous concentrated alloys -- VIII. Superionic conductors -- IX. Amorphous materials -- CHAPTER VI: DIFFUSION AND DRIFT IN ALLOYS AND COMPOUNDS -- I. Intrinsic diffusion coefficients -- II. The interdiffusion coefficient -- III. Chemical diffusion in compounds -- IV. The effective diffusion coefficient -- APPENDIX I: Variable molar volume. Problem of the frame of reference -- APPENDIX II: Kröger-Vink notation -- APPENDIX III: Deviation from stoichiometry in a binary oxide -- APPENDIX IV: Ambipolar diffusion in a binary oxide -- CHAPTER VII: DIFFUSION IN MEDIA OF LOWER DIMENSIONALITY -- PART 1. - INTERNAL SHORT-CIRCUITS (dislocations, interfaces) -- I. Phenomenology -- II. Analytical solutions -- III. Atomic models -- IV. Effect of temperature -- V. Experimental methods and results -- VI. Diffusion-induced grain-boundary migration (DIGM) -- PART 2. - SURFACE DIFFUSION -- I. The structure of surfaces -- II. Mechanisms of diffusion -- III. Experimental methods and results -- APPENDIX I: Grain-boundary diffusion -- APPENDIX II: Evolution of the profile of a surface by material transport -- CHAPTER VIII: PHENOMENOLOGICAL THEORY OF DIFFUSION -- I. Review of the Thermondynamics of Irreversible Processes (T.I.P.) -- II. The application of T.I.P. to diffusion in solids -- III. Applications of the phenomenological equations -- IV. Ternary systems -- V. Heterogeneous solid solutions: effect of composition gradients -- APPENDIX I: Chemical potential of vacancies.
APPENDIX II: Diffusion in anisotropic media -- APPENDIX III: The frame of reference -- APPENDIX IV: The square root diffusivity -- CHAPTER IX: TECHNIQUES FOR THE STUDY OF DIFFUSION -- PART 1. - DIFFUSION OVER A LONG DISTANCE -- I. Methodology of the measurements. Sample preparation -- II. Determination of the diffusion profile c (x, y, z , t ) -- III. Indirect methods -- IV. Data processing -- PART 2. - METHODS BASED ON THE MEASUREMENT OF JUMP FREQUENCIES -- I. Relaxation induced by an external stimulus -- II. Nuclear methods -- PART 3. - COMPUTER SIMULATION -- I. Statistical calculations -- II. Defect characteristics and diffusion mechanisms -- APPENDIX I: Diffusion of gases -- APPENDIX II: The Snoek effect -- CHAPTER X: THE STUDY OF SOME DIFFUSION-CONTROLLED PROCESSES -- I. Diffusion in multi-phase systems and the formation of intermediate compounds -- II. Oxidation -- III. Sintering -- IV. Precipitation and Aging -- V. The solidification of an alloy -- VI. Diffusion under irradiation -- VII. Plastic deformation at high temperature -- APPENDIX I: Rate constant for oxidation -- APPENDIX II: Effective diffusion coefficient for coalescence -- APPENDIX III: Growth of voids at grain boundaries during high-temperature deformation -- Exercises -- Index.
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Intro -- TABLE OF CONTENTS -- Preface -- Foreword -- Foreword to the English edition -- Translator's acknowledgments -- General Bibliography -- Notation -- CHAPTER I: DIFFUSION AND DRIFT -- I. Flux of particles. Fick's equation -- II. Time-dependent case -- III. Solutions of the diffusion equation (or Fick's second law) -- IV. Relation between drift and diffusion. The Nernst-Einstein equation -- V. The nature of the driving force -- VI. A variety of diffusion processes and generalization of Fick's law -- VII. Diffusion with phase change. Multiphase diffusion -- APPENDIX I: Methods for solving the diffusion equation -- APPENDIX II: Diffusion in three dimensions -- APPENDIX III: Conservation at a moving boundary -- CHAPTER II: ATOMIC THEORY OF DIFFUSION -- I. A simplified model -- II. General theory of random walk -- III. Expressions for the mean-square displacement (X²) and for the diffusion coefficient -- IV. Diffusion in the presence of a driving force -- V. Explicit form of the function W (X, pi) -- VI. Variable jump distance -- VII. Correlation functions -- VIII. Limitations of Fick's law -- APPENDIX: Some definitions -- CHAPTER III: DIFFUSION MECHANISMS AND CORRELATION EFFECTS -- I. Mechanisms of diffusion -- II. Definition of the correlation factor -- III. The encounter model -- IV. A simple simulation of self-diffusion and electromigration -- V. Methods of calculating the correlation factor -- VI. Types of correlation factors -- VII. Migration of point defects -- Effect of temperature -- APPENDIX I: Calculation of (cos theta) -- APPENDIX II: Percolation -- CHAPTER IV: SELF-DIFFUSION -- I. The self-diffusion coefficient -- II. Variation of the diffusion coefficient with temperature -- III. Anisotropy of diffusion -- IV. Deviations from the Arrhenius law -- V. The isotope effect -- VI. Effect of pressure -- VII. Empirical correlations.

VIII. Self-diffusion in metals -- IX. Self-diffusion in semiconductors -- X. Semi-diffusion in ionic crystals -- XI. Molecular crystals -- CHAPTER V: SOLUTE DIFFUSION IN PURE MATERIALS. DIFFUSION IN ALLOYS -- I. Introduction -- II. Solute diffusion at infinite dilution -- III. Interstitial solid solutions -- IV. Ionic crystals -- V. Semiconductors -- VI. Dilute alloys -- VII. Diffusion in homogeneous concentrated alloys -- VIII. Superionic conductors -- IX. Amorphous materials -- CHAPTER VI: DIFFUSION AND DRIFT IN ALLOYS AND COMPOUNDS -- I. Intrinsic diffusion coefficients -- II. The interdiffusion coefficient -- III. Chemical diffusion in compounds -- IV. The effective diffusion coefficient -- APPENDIX I: Variable molar volume. Problem of the frame of reference -- APPENDIX II: Kröger-Vink notation -- APPENDIX III: Deviation from stoichiometry in a binary oxide -- APPENDIX IV: Ambipolar diffusion in a binary oxide -- CHAPTER VII: DIFFUSION IN MEDIA OF LOWER DIMENSIONALITY -- PART 1. - INTERNAL SHORT-CIRCUITS (dislocations, interfaces) -- I. Phenomenology -- II. Analytical solutions -- III. Atomic models -- IV. Effect of temperature -- V. Experimental methods and results -- VI. Diffusion-induced grain-boundary migration (DIGM) -- PART 2. - SURFACE DIFFUSION -- I. The structure of surfaces -- II. Mechanisms of diffusion -- III. Experimental methods and results -- APPENDIX I: Grain-boundary diffusion -- APPENDIX II: Evolution of the profile of a surface by material transport -- CHAPTER VIII: PHENOMENOLOGICAL THEORY OF DIFFUSION -- I. Review of the Thermondynamics of Irreversible Processes (T.I.P.) -- II. The application of T.I.P. to diffusion in solids -- III. Applications of the phenomenological equations -- IV. Ternary systems -- V. Heterogeneous solid solutions: effect of composition gradients -- APPENDIX I: Chemical potential of vacancies.

APPENDIX II: Diffusion in anisotropic media -- APPENDIX III: The frame of reference -- APPENDIX IV: The square root diffusivity -- CHAPTER IX: TECHNIQUES FOR THE STUDY OF DIFFUSION -- PART 1. - DIFFUSION OVER A LONG DISTANCE -- I. Methodology of the measurements. Sample preparation -- II. Determination of the diffusion profile c (x, y, z , t ) -- III. Indirect methods -- IV. Data processing -- PART 2. - METHODS BASED ON THE MEASUREMENT OF JUMP FREQUENCIES -- I. Relaxation induced by an external stimulus -- II. Nuclear methods -- PART 3. - COMPUTER SIMULATION -- I. Statistical calculations -- II. Defect characteristics and diffusion mechanisms -- APPENDIX I: Diffusion of gases -- APPENDIX II: The Snoek effect -- CHAPTER X: THE STUDY OF SOME DIFFUSION-CONTROLLED PROCESSES -- I. Diffusion in multi-phase systems and the formation of intermediate compounds -- II. Oxidation -- III. Sintering -- IV. Precipitation and Aging -- V. The solidification of an alloy -- VI. Diffusion under irradiation -- VII. Plastic deformation at high temperature -- APPENDIX I: Rate constant for oxidation -- APPENDIX II: Effective diffusion coefficient for coalescence -- APPENDIX III: Growth of voids at grain boundaries during high-temperature deformation -- Exercises -- Index.

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Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2024. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.

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