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Asymmetric Heterogeneous Supported Catalysis : Use of Nitrogen-Containing LigandsRUSH.

By: Contributor(s): Material type: TextTextSeries: Polymer Science and TechnologyPublisher: Hauppauge : Nova Science Publishers, Incorporated, 2012Copyright date: ©2011Edition: 1st edDescription: 1 online resource (185 pages)Content type:
  • text
Media type:
  • computer
Carrier type:
  • online resource
ISBN:
  • 9781617281013
Subject(s): Genre/Form: Additional physical formats: Print version:: Asymmetric Heterogeneous Supported CatalysisDDC classification:
  • 541/.395
LOC classification:
  • QD505 -- .S2545 2011eb
Online resources:
Contents:
Intro -- ASYMMETRIC HETEROGENEOUS SUPPORTED CATALYSIS: USE OF NITROGEN-CONTAINING LIGANDS -- Library of Congress Cataloging-in-Publication Data -- Contents -- Preface -- Chapter 1: Introduction -- Chapter 2: Reduction of C=O and C=N Bond -- 2.1. Hydrogenation -- 2.2. Hydrogenation Transfer Reduction -- 2.2.1. 1,2-Diamine and Derivatives -- 2.2.2. Imprinting Technique for Hydrogen Transfer Reduction with 1,2-Diamines -- 2.2.3. Aminoalcohol as Ligand -- 2.2.4. Dialdimine Ligand as Ligand -- 2.3. Enantioselective Hydride Reduction -- 2.4. Hydrosilylation with Ligands as Pendent Group -- 2.5. Reduction of C=N bond -- Chapter 3: Cyclopropanation -- 3.1. Oxazolines Ligands -- 3.1.1. Insoluble Supported-Polymer Box a Ligands -- 3.1.2. Insoluble Supported-Polymer AzaBOX as Ligands -- 3.1.3. Insoluble Supported-Polymer PyBox as Ligands -- 3.1.4. Immobilization of PyBox on Natural Polymers -- 3.1.5. Soluble Supported-Polymer Box as Ligands -- 3.1.6. Soluble Supported-Polymer AzaBox as Ligands -- 3.2. Porphyrins -- 3.3. Miscellaneous -- Chapter 4: Cycloadditions and Heterocycloadditions -- 4.1. Supported Box Ligands -- 4.2. Supported Aminoalcohol and N-Sulfonylamino Acid-Derived Oxazaborolidine or Oxazaborolidinone -- 4.3. Supported Salen as Ligand -- Chapter 5: Addition of Organometallic Reagents to Aldehydes, Ketones and Imines -- 5.1. Supported Aminoalcohols as Ligands -- 5.2. Supported Sulfonamide -- and N-Sulfonylated Aminoalcohols -- 5.3. Supported Oxazoline -- or Oxazolidine as Ligands -- 5.4. Supported Salen as Chiral Ligands -- Chapter 6: Asymmetric (-Allylic Substitution -- Chapter 7: Dihydroxylation and Aminohydroxylation -- 7.1. Insoluble Supported Alkaloid as Ligand -- 7.2. Soluble Supported Alkaloid as Ligand -- Chapter 8: Epoxidation -- 8.1. Supported Salen as Ligand -- 8.2. Porphyrins -- 8.3. Soluble Polymers.
Chapter 9: Kinetic Resolution of Terminal Epoxides -- Chapter 10: Miscellaneous -- Chapter 11: Conclusion -- References -- Index.
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Intro -- ASYMMETRIC HETEROGENEOUS SUPPORTED CATALYSIS: USE OF NITROGEN-CONTAINING LIGANDS -- Library of Congress Cataloging-in-Publication Data -- Contents -- Preface -- Chapter 1: Introduction -- Chapter 2: Reduction of C=O and C=N Bond -- 2.1. Hydrogenation -- 2.2. Hydrogenation Transfer Reduction -- 2.2.1. 1,2-Diamine and Derivatives -- 2.2.2. Imprinting Technique for Hydrogen Transfer Reduction with 1,2-Diamines -- 2.2.3. Aminoalcohol as Ligand -- 2.2.4. Dialdimine Ligand as Ligand -- 2.3. Enantioselective Hydride Reduction -- 2.4. Hydrosilylation with Ligands as Pendent Group -- 2.5. Reduction of C=N bond -- Chapter 3: Cyclopropanation -- 3.1. Oxazolines Ligands -- 3.1.1. Insoluble Supported-Polymer Box a Ligands -- 3.1.2. Insoluble Supported-Polymer AzaBOX as Ligands -- 3.1.3. Insoluble Supported-Polymer PyBox as Ligands -- 3.1.4. Immobilization of PyBox on Natural Polymers -- 3.1.5. Soluble Supported-Polymer Box as Ligands -- 3.1.6. Soluble Supported-Polymer AzaBox as Ligands -- 3.2. Porphyrins -- 3.3. Miscellaneous -- Chapter 4: Cycloadditions and Heterocycloadditions -- 4.1. Supported Box Ligands -- 4.2. Supported Aminoalcohol and N-Sulfonylamino Acid-Derived Oxazaborolidine or Oxazaborolidinone -- 4.3. Supported Salen as Ligand -- Chapter 5: Addition of Organometallic Reagents to Aldehydes, Ketones and Imines -- 5.1. Supported Aminoalcohols as Ligands -- 5.2. Supported Sulfonamide -- and N-Sulfonylated Aminoalcohols -- 5.3. Supported Oxazoline -- or Oxazolidine as Ligands -- 5.4. Supported Salen as Chiral Ligands -- Chapter 6: Asymmetric (-Allylic Substitution -- Chapter 7: Dihydroxylation and Aminohydroxylation -- 7.1. Insoluble Supported Alkaloid as Ligand -- 7.2. Soluble Supported Alkaloid as Ligand -- Chapter 8: Epoxidation -- 8.1. Supported Salen as Ligand -- 8.2. Porphyrins -- 8.3. Soluble Polymers.

Chapter 9: Kinetic Resolution of Terminal Epoxides -- Chapter 10: Miscellaneous -- Chapter 11: Conclusion -- References -- Index.

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Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2024. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.

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