Advances in Organic Synthesis : Volume 13.

Cover -- Title -- Copyright -- End User License Agreement -- Contents -- Preface -- List of Contributors -- Remarkable Advances in the Asymmetric Synthesis of Biologically Active Natural Compounds from the Advent of Chiral Auxiliaries -- Gaspar Diaz-Muñoz1,*, Izabel Luzia Miranda1, Suélen Karine Sartori1, Daniele Cristina de Rezende1, Jefferson Viktor Barros de Paula Baeta2, Fernanda Rodrigues Nascimento2 and Marisa Alves Nogueira Diaz2 -- INTRODUCTION -- EVANS' OXAZOLIDINONES -- Asymmetric Aldol Reactions by Using Evans' Oxazolidinones -- Preparation of the Spiroketal Subunit (1) -- Preparation of the Polyol Glycoside Subunit (2) -- Synthesis of (−)-Cytovaricin -- COREY'S CHIRAL AUXILIARY: (+)-8-PHENYLMENTHOL -- ENDERS' CHIRAL AUXILIARIES -- CHIRAL AUXILIARIES OF YAMADA -- OPPOLZER'S CHIRAL AUXILIARY -- CARBOHYDRATES AS CHIRAL AUXILIARIES - KUNZ'S AUXILIARIES -- Asymmetric Reaction of Strecker Employing Kunz's Galactosylamine -- Asymmetric Mannich Reaction Employing the Galactosylamine of Kunz -- MEYERS CHIRAL OXAZOLINES -- AMINO ACIDS AS CHIRAL AUXILIARIES - SCHÖLLKOPF AUXILIARIES -- CONCLUSIONS -- LIST OF ABBREVIATIONS -- CONSENT FOR PUBLICATION -- CONFLICT OF INTEREST -- ACKNOWLEDGEMENTS -- REFERENCES -- The Chemistry of Ynamide and Its Application in Organic Synthesis -- Siyu Ye1 and Na Wu1,2,* -- INTRODUCTION -- PREPARATIONS OF YNAMIDES -- Dehydrohalogenation -- Alkynyliodonium Salts -- Ullmann Coupling of Amides -- Oxidative Coupling -- Functionalization of Terminal Ynamides -- Strained Cyclic Ynamide -- REACTIONS OF YNAMIDES -- Addition Reaction -- Addition to α-Position of Ynamides -- With Carbon-Halogen Bond Formation -- With Carbon-Oxygen Bond Formation -- With Carbon-Carbon Bond Formation -- With Carbon-Nitrogen Bond Formation -- Addition to β-Position of Ynamides -- With Carbon-Boron Bond Formation.

With Carbon-Carbon Bond Formation -- With Carbon-Phosphorus Bond Formation -- With Carbon-Nitrogen Bond Formation -- With Carbon-Silicon Bond Formation -- Radical Process -- Oxidation -- Rearrangement -- Cyclization -- Metal-Free or Lewis Acid Mediated Cyclization -- Gold-Mediated Cyclization -- Copper-Mediated Cyclization -- Palladium-Mediated Cyclization -- Rhodium-Mediated Cyclization -- Cycloaddition -- [2+1] -- [2+2] -- [3+2] -- [4+1] -- [4+2] -- [2+2+2] -- [5+2] -- CONCLUSION -- CONSENT FOR PUBLICATION -- CONFLICT OF INTEREST -- ACKNOWLEDGEMENTS -- REFERENCES -- Carbon-Heteroatom Bond Formation for Medium Ring Heterocycles -- Bhaskar Chatterjee1, Prateek Bhamboo2, Dhananjoy Mondal2 and Smritilekha Bera2,* -- INTRODUCTION -- STRUCTURAL EFFECTS -- RINGS WITH HETEROATOMS OTHER THAN O, N, AND S -- SYNTHETIC METHODS -- STRATEGIES FOR C-X BOND FORMATION -- SYNTHESIS OF 7-MEMBERED RINGS -- TRANSITION METAL CATALYZED REACTIONS -- GREEN SYNTHESIS -- NUCLEOPHILIC CYCLIZATION -- REARRANGEMENT REACTIONS -- SYNTHESIS OF 8-MEMBERED RINGS -- TRANSITION METAL CATALYZED REACTIONS -- NUCLEOPHILIC CYCLIZATION -- REARRANGEMENT REACTIONS -- SYNTHESIS OF 9-MEMBERED RINGS -- Transition Metal Catalyzed Reactions -- NUCLEOPHILIC CYCLIZATION -- OXIDATIVE REARRANGEMENTS -- CONCLUSION -- CONFLICT OF INTEREST -- ACKNOWLEDGEMENTS -- LIST OF ABBREVIATIONS -- REFERENCES -- Tin(II) Salts: A Versatile and Efficient Lewis Acid Catalyst in Reactions to Add Value to the Glycerol and Terpenic Alcohols -- Marcio J. da Silva* and Milena G. Teixeira -- INTRODUCTION -- Sncl2 Or Snf2-Catalyzed Solketal Synthesis -- Sn(II)-Catalyzed Terpenic Alcohol Esterification With Acetic Acid -- CONCLUDING REMARKS -- CONSENT FOR PUBLICATION -- CONFLICT OF INTEREST -- ACKNOWLEDGEMENTS -- REFERENCES.

(E)-N-Methyl-1-(Methylthio)-2-Nitroethenamine (Nmsm) as a Versatile Ambiphilic Synthon in Organic Synthesis -- Pedavenkatagari Narayana Reddy1,* and Pannala Padmaja2,* -- INTRODUCTION -- Preparation of NMSM -- APPLICATIONS OF NMSM IN THE SYNTHESIS OF HETEROCYCLES -- Single Ring Heterocyclic Derivatives -- Dihydropyridines -- Pyridones -- 4h-Pyrans -- Pyrimidinones -- Pyrroles -- Thiophenes -- Isoxazoles -- Fused heterocycle derivatives -- 4H-chromenes -- 4h-Chromenones -- Pyranochromenones -- Benzochromenes -- Benzochromene-Diones -- Pyranocarbazoles -- Pyranopyrazoles -- Pyranopyranones -- Pyranoquinolinones -- Pyrazolopyridines -- Pyranopyrimidines -- Imidazopyrimidines -- Indenopyrroles -- Bis-Heterocyclic Compounds -- Indolylpyrans -- Chromenopyrazoles -- Pyrrolylpyrimidines -- Spiroheterocycles -- Spiroindolines -- Spiro-4h-Pyrans -- Bulk Drug Synthesis (Industrial Applications) -- Ranitidine -- Nizatidine -- CONCLUSION -- CONSENT FOR PUBLICATION -- CONFLICT OF INTEREST -- ACKNOWLEDGEMENTS -- REFERENCES -- Subject Index -- Back Cover.

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Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2024. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.